biostudies-literature00560Unknown70(Pt 7)Soury RThe asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an anti-mony(V) tetra-phenyl-porphyrin complex cation and one half of an hexa-chlorido-anti-monate(V) anion. In the complex cation, the Sb(V) atom lies on an inversion center and is octa-hedrally coordinated by four N atoms from a macrocyclic tetra-phenyl-porphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018?(5)?Å from the porphyrin mean plane. The average Sb-N distance is 2.062?(11)?Å, while the Sb-Cl distance is 2.355?(1)?Å. The Sb(V) atom of the anion is also located on an inversion center. The [SbCl6](-) octa-hedron exhibits rhombic distortion characterized by the Sb-Cl bond lengths [2.311?(3), 2.374?(2) and 2.393?(4)?Å]. In the crystal, the cations and anions are linked C-H? Cl hydrogen bonds, forming a layer parallel to (211).Acta crystallographica. Section E, Structure reports onlinem256-7https://www.ebi.ac.uk/biostudies/studies/S-EPMC4120531biostudies-literatureDi-chlorido-(5,10,15,20-tetra-phenyl-porphyrinato-?(4) N)anti-mony(V) hexa-chlorido-anti-monate(V).PMC4120531Giorgi MSoury RNasri HBelkhiria MS56falseDi-chlorido-(5,10,15,20-tetra-phenyl-porphyrinato-?(4) N)anti-mony(V) hexa-chlorido-anti-monate(V).The asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an anti-mony(V) tetra-phenyl-porphyrin complex cation and one half of an hexa-chlorido-anti-monate(V) anion. In the complex cation, the Sb(V) atom lies on an inversion center and is octa-hedrally coordinated by four N atoms from a macrocyclic tetra-phenyl-porphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018?(5)?Å from the porphyrin mean plane. The average Sb-N distance is 2.062?(11)?Å, while the Sb-Cl distance is 2.355?(1)?Å. The Sb(V) atom of the anion is also located on an inversion center. The [SbCl6](-) octa-hedron exhibits rhombic distortion characterized by the Sb-Cl bond lengths [2.311?(3), 2.374?(2) and 2.393?(4)?Å]. In the crystal, the cations and anions are linked C-H? Cl hydrogen bonds, forming a layer parallel to (211).2014-01-01T00:00:00Z2014 Jul2021-02-21T10:17:58Z2019-03-27T01:33:20ZS-EPMC41205312516152210.1107/S1600536814012653