{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["10"],"submitter":["Tonoi T"],"pubmed_abstract":["The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson-Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization."],"journal":["Beilstein journal of organic chemistry"],"pagination":["2421-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4222296"],"repository":["biostudies-literature"],"pubmed_title":["Total synthesis of the proposed structure of astakolactin."],"pmcid":["PMC4222296"],"pubmed_authors":["Shiina I","Mameda K","Tonoi T","Yoshinaga Y","Fujishiro M"],"additional_accession":[]},"is_claimable":false,"name":"Total synthesis of the proposed structure of astakolactin.","description":"The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson-Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization.","dates":{"release":"2014-01-01T00:00:00Z","publication":"2014","modification":"2025-04-18T16:18:06.074Z","creation":"2019-03-27T01:38:59Z"},"accession":"S-EPMC4222296","cross_references":{"pubmed":["25383112"],"doi":["10.3762/bjoc.10.252"]}}