<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>71(Pt 3)</volume><submitter>Beghidja N</submitter><pubmed_abstract>The lactone ring in the title mol-ecule, C15H22O3 (systematic name: 3,4a,8-tri-methyl-dodeca-hydro-azuleno[6,5-b]furan-2,5-dione), assumes an envelope conformation with the methine C atom adjacent to the the methine C atom carrying the methyl substituent being the flap atom. The other five-membered ring adopts a twisted conformation with the twist being about the methine-methyl-ene C-C bond. The seven-membered ring is based on a twisted boat conformation. No specific inter-actions are noted in the the crystal packing.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>o162</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC4350757</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of pseudoguainolide.</pubmed_title><pmcid>PMC4350757</pmcid><pubmed_authors>Benayache S</pubmed_authors><pubmed_authors>Kariuki BM</pubmed_authors><pubmed_authors>Knight DW</pubmed_authors><pubmed_authors>Beghidja N</pubmed_authors><pubmed_authors>Benayache F</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of pseudoguainolide.</name><description>The lactone ring in the title mol-ecule, C15H22O3 (systematic name: 3,4a,8-tri-methyl-dodeca-hydro-azuleno[6,5-b]furan-2,5-dione), assumes an envelope conformation with the methine C atom adjacent to the the methine C atom carrying the methyl substituent being the flap atom. The other five-membered ring adopts a twisted conformation with the twist being about the methine-methyl-ene C-C bond. The seven-membered ring is based on a twisted boat conformation. No specific inter-actions are noted in the the crystal packing.</description><dates><release>2015-01-01T00:00:00Z</release><publication>2015 Mar</publication><modification>2024-10-14T22:34:24.107Z</modification><creation>2019-03-27T01:47:39Z</creation></dates><accession>S-EPMC4350757</accession><cross_references><pubmed>25844227</pubmed><doi>10.1107/S2056989015002510</doi></cross_references></HashMap>