{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["71(Pt 2)"],"submitter":["Suckert S"],"pubmed_abstract":["In the crystal structure of the title compound, [Ni(NCS)2(H2O)4]·4C6H8N2, the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thio-cyanate anions in a slightly distorted octa-hedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water mol-ecules and one thio-cyanate ligand, as well as two uncoordinated 2,5-di-methyl-pyrazine ligands in general positions. In the crystal, discrete complex mol-ecules are linked into a three-dimensional network by O-H⋯N hydrogen bonding between the water H atoms and the 2,5-di-methyl-pyrazine N atoms."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["m18"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4384548"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of tetra-aqua-bis-(thio-cyanato-κN)nickel(II)-2,5-di-methyl-pyrazine (1/4)."],"pmcid":["PMC4384548"],"pubmed_authors":["Wriedt M","Nather C","Suckert S","Jess I"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of tetra-aqua-bis-(thio-cyanato-κN)nickel(II)-2,5-di-methyl-pyrazine (1/4).","description":"In the crystal structure of the title compound, [Ni(NCS)2(H2O)4]·4C6H8N2, the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thio-cyanate anions in a slightly distorted octa-hedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water mol-ecules and one thio-cyanate ligand, as well as two uncoordinated 2,5-di-methyl-pyrazine ligands in general positions. In the crystal, discrete complex mol-ecules are linked into a three-dimensional network by O-H⋯N hydrogen bonding between the water H atoms and the 2,5-di-methyl-pyrazine N atoms.","dates":{"release":"2015-01-01T00:00:00Z","publication":"2015 Feb","modification":"2025-04-22T10:28:43.048Z","creation":"2019-03-27T01:49:20Z"},"accession":"S-EPMC4384548","cross_references":{"pubmed":["25878833"],"doi":["10.1107/S2056989014026991"]}}