{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["71(Pt 5)"],"submitter":["Laachir A"],"pubmed_abstract":["In the mononuclear title complex, [Co(N3)2(C12H8N4S)2], the cobalt(II) atom is located on an inversion centre and displays an axially weakly compressed octa-hedral coordination geometry. The equatorial positions are occupied by the N atoms of two 2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole ligands, whereas the axial positions are occupied by N atoms of the azide anions. The thia-diazole and pyridine rings linked to the metal are almost coplanar, with a maximum deviation from the mean plane of 0.0273 (16) Å. The cohesion of the crystal is ensured by weak C-H⋯N hydrogen bonds and by π-π inter-actions between pyridine rings [inter-centroid distance = 3.6356 (11) Å], forming a layered arrangement parallel to (001). The structure of the title compound is isotypic with that of the analogous nickel(II) complex [Laachir et al. (2013 ▶). Acta Cryst. E69, m351-m352]."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["452-4"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4420119"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of bis-(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia-diazole-κ(2) N (2),N (3)]cobalt(II)."],"pmcid":["PMC4420119"],"pubmed_authors":["Laachir A","El Ammari L","Saadi M","Guesmi S","Bentiss F"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of bis-(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thia-diazole-κ(2) N (2),N (3)]cobalt(II).","description":"In the mononuclear title complex, [Co(N3)2(C12H8N4S)2], the cobalt(II) atom is located on an inversion centre and displays an axially weakly compressed octa-hedral coordination geometry. The equatorial positions are occupied by the N atoms of two 2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole ligands, whereas the axial positions are occupied by N atoms of the azide anions. The thia-diazole and pyridine rings linked to the metal are almost coplanar, with a maximum deviation from the mean plane of 0.0273 (16) Å. The cohesion of the crystal is ensured by weak C-H⋯N hydrogen bonds and by π-π inter-actions between pyridine rings [inter-centroid distance = 3.6356 (11) Å], forming a layered arrangement parallel to (001). The structure of the title compound is isotypic with that of the analogous nickel(II) complex [Laachir et al. (2013 ▶). Acta Cryst. E69, m351-m352].","dates":{"release":"2015-01-01T00:00:00Z","publication":"2015 May","modification":"2025-04-27T00:55:33.937Z","creation":"2019-03-27T01:51:01Z"},"accession":"S-EPMC4420119","cross_references":{"pubmed":["25995853"],"doi":["10.1107/S2056989015006544"]}}