biostudies-literatureWeber MNIGMS NIH HHS3600-3603https://www.ebi.ac.uk/biostudies/studies/S-EPMC4445844biostudies-literatureUnknown56(23)A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.Tetrahedron lettersAtropurpuran - Missing Biosynthetic Link Leading to the Hetidine and Arcutine C₂₀-Diterpenoid Alkaloids or an Oxidative Degradation Product?PMC4445844R01 GM084906Weber MOwens KSarpong RfalseAtropurpuran - Missing Biosynthetic Link Leading to the Hetidine and Arcutine C₂₀-Diterpenoid Alkaloids or an Oxidative Degradation Product?A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.2015-01-01T00:00:00Z2015 Jun2025-04-18T17:30:41.882Z2019-03-27T01:52:14ZS-EPMC44458442602878910.1016/j.tetlet.2015.01.111