{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Primer DN"],"funding":["Pfizer","National Institutes of Health","NIGMS NIH HHS","Tubitak"],"pagination":["2195-8"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4466116"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["137(6)"],"pubmed_abstract":["Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates with an array of aryl bromides mediated by an Ir photoredox catalyst and a Ni cross-coupling catalyst."],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling."],"pmcid":["PMC4466116"],"funding_grant_id":["R01 GM081376","NIGMS R01 GM081376"],"pubmed_authors":["Karakaya I","Molander GA","Primer DN","Tellis JC"],"additional_accession":[]},"is_claimable":false,"name":"Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling.","description":"Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates with an array of aryl bromides mediated by an Ir photoredox catalyst and a Ni cross-coupling catalyst.","dates":{"release":"2015-01-01T00:00:00Z","publication":"2015 Feb","modification":"2026-05-01T14:48:41.909Z","creation":"2026-04-07T17:03:21.01Z"},"accession":"S-EPMC4466116","cross_references":{"pubmed":["25650892"],"doi":["10.1021/ja512946e"]}}