{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["6"],"submitter":["Wu F"],"pubmed_abstract":["The ability to modulate the spin states of adsorbed molecules is in high demand for molecular spintronics applications. Here, we demonstrate that the spin state of a corrole complex can be tuned by expanding its fused ring as a result of the modification to the d-π interaction between the metal and ligand. A bicyclo[2.2.2]octadiene-fused copper corrole can readily be converted into a tetrabenzocorrole radical on an Au(111) substrate during the sublimation process. In the scanning tunnelling spectroscopy spectrum, a sharp Kondo resonance appears near the Fermi level on the corrole ligand of the tetrabenzocorrole molecule. In contrast, a non-fused-ring-expanded copper corrole molecule, copper 5,10,15-triphenylcorrole, shows no such Kondo feature. Mapping of the Kondo resonance demonstrates t"],"journal":["Nature communications"],"pagination":["7547"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4491828"],"repository":["biostudies-literature"],"pubmed_title":["Modulation of the molecular spintronic properties of adsorbed copper corroles."],"pmcid":["PMC4491828"],"pubmed_authors":["Liu J","Shen Z","Mishra P","Komeda T","Mack J","Wu F","Chang Y","Kobayashi N"],"additional_accession":[]},"is_claimable":false,"name":"Modulation of the molecular spintronic properties of adsorbed copper corroles.","description":"The ability to modulate the spin states of adsorbed molecules is in high demand for molecular spintronics applications. Here, we demonstrate that the spin state of a corrole complex can be tuned by expanding its fused ring as a result of the modification to the d-π interaction between the metal and ligand. A bicyclo[2.2.2]octadiene-fused copper corrole can readily be converted into a tetrabenzocorrole radical on an Au(111) substrate during the sublimation process. In the scanning tunnelling spectroscopy spectrum, a sharp Kondo resonance appears near the Fermi level on the corrole ligand of the tetrabenzocorrole molecule. In contrast, a non-fused-ring-expanded copper corrole molecule, copper 5,10,15-triphenylcorrole, shows no such Kondo feature. Mapping of the Kondo resonance demonstrates t","dates":{"release":"2015-01-01T00:00:00Z","publication":"2015 Jun","modification":"2025-04-04T11:06:42.744Z","creation":"2019-03-27T01:54:34Z"},"accession":"S-EPMC4491828","cross_references":{"pubmed":["26112968"],"doi":["10.1038/ncomms8547"]}}