<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>71(Pt 11)</volume><submitter>Goodman MA</submitter><pubmed_abstract>The title mol-ecule, C13H16N6, crystallizes from hexane as a mol-ecular crystal with no strong inter-molecular inter-actions (the shortest C-H⋯N contact is longer than 3.38 Å). A relatively short intra-molecular contact (3.09 Å) has a C-H⋯N angle of 118° which is quite small to be still considered a hydrogen bond. The three pyrazole rings form a propeller-like motif, with one methylpyrazole unit almost perpendicular to the mean plane of the three rings [82.20 (6)°]. The other two methylpyrazole units, with nitrogen donor atoms oriented in opposite directions, are oriented at 67.26 (6) and 72.53 (6)° to the mean plane.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>o816</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC4645007</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of tris-(3-methyl-1H-pyrazol-1-yl)methane.</pubmed_title><pmcid>PMC4645007</pmcid><pubmed_authors>Goodman MA</pubmed_authors><pubmed_authors>Patel EN</pubmed_authors><pubmed_authors>Goodman MS</pubmed_authors><pubmed_authors>Nazarenko AY</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of tris-(3-methyl-1H-pyrazol-1-yl)methane.</name><description>The title mol-ecule, C13H16N6, crystallizes from hexane as a mol-ecular crystal with no strong inter-molecular inter-actions (the shortest C-H⋯N contact is longer than 3.38 Å). A relatively short intra-molecular contact (3.09 Å) has a C-H⋯N angle of 118° which is quite small to be still considered a hydrogen bond. The three pyrazole rings form a propeller-like motif, with one methylpyrazole unit almost perpendicular to the mean plane of the three rings [82.20 (6)°]. The other two methylpyrazole units, with nitrogen donor atoms oriented in opposite directions, are oriented at 67.26 (6) and 72.53 (6)° to the mean plane.</description><dates><release>2015-01-01T00:00:00Z</release><publication>2015 Nov</publication><modification>2025-04-18T23:09:31.757Z</modification><creation>2019-03-27T02:01:57Z</creation></dates><accession>S-EPMC4645007</accession><cross_references><pubmed>26594542</pubmed><doi>10.1107/S2056989015017247</doi></cross_references></HashMap>