{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Krap CP"],"funding":["European Research Council","University of Manchester","Consejo Nacional de Ciencia y Tecnolog?a","University of Nottingham","Engineering and Physical Sciences Research Council"],"pagination":["1076-88"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4805307"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["55(3)"],"pubmed_abstract":["Metal-organic frameworks (MOFs) are usually synthesized using a single type of metal ion, and MOFs containing mixtures of different metal ions are of great interest and represent a methodology to enhance and tune materials properties. We report the synthesis of [Ga2(OH)2(L)] (H4L = biphenyl-3,3',5,5'-tetracarboxylic acid), designated as MFM-300(Ga2), (MFM = Manchester Framework Material replacing NOTT designation), by solvothermal reaction of Ga(NO3)3 and H4L in a mixture of DMF, THF, and water containing HCl for 3 days. MFM-300(Ga2) crystallizes in the tetragonal space group I4122, a = b = 15.0174(7) Å and c = 11.9111(11) Å and is isostructural with the Al(III) analogue MFM-300(Al2) with pores decorated with -OH groups bridging Ga(III) centers. The isostructural Fe-doped material [Ga(1.87"],"journal":["Inorganic chemistry"],"pubmed_title":["Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga2(OH)2(L)] (H4L = Biphenyl-3,3',5,5'-tetracarboxylic Acid), MFM-300(Ga2)."],"pmcid":["PMC4805307"],"funding_grant_id":["1069418","EP/I011870/1","EP/I011870/2","1225338","EP/K038869/1","EP/P001386/1"],"pubmed_authors":["Cinque G","Allan DR","Savage M","Easun TL","Schroder M","Beton PH","Dhakshinamoorthy A","Lewis W","Krap CP","Cebula I","Newby R","Tang CC","Warren MR","Garcia H","Eyley JE","Yang S","Gao S","Blake AJ","Frogley MD"],"additional_accession":[]},"is_claimable":false,"name":"Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga2(OH)2(L)] (H4L = Biphenyl-3,3',5,5'-tetracarboxylic Acid), MFM-300(Ga2).","description":"Metal-organic frameworks (MOFs) are usually synthesized using a single type of metal ion, and MOFs containing mixtures of different metal ions are of great interest and represent a methodology to enhance and tune materials properties. We report the synthesis of [Ga2(OH)2(L)] (H4L = biphenyl-3,3',5,5'-tetracarboxylic acid), designated as MFM-300(Ga2), (MFM = Manchester Framework Material replacing NOTT designation), by solvothermal reaction of Ga(NO3)3 and H4L in a mixture of DMF, THF, and water containing HCl for 3 days. MFM-300(Ga2) crystallizes in the tetragonal space group I4122, a = b = 15.0174(7) Å and c = 11.9111(11) Å and is isostructural with the Al(III) analogue MFM-300(Al2) with pores decorated with -OH groups bridging Ga(III) centers. The isostructural Fe-doped material [Ga(1.87","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Feb","modification":"2026-04-14T21:13:45.67Z","creation":"2019-03-27T03:10:09Z"},"accession":"S-EPMC4805307","cross_references":{"pubmed":["26757137"],"doi":["10.1021/acs.inorgchem.5b02108"]}}