{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["12"],"submitter":["D'yakonov VA"],"pubmed_abstract":["An efficient one-pot process for the synthesis of 3-substituted phospholanes and α,ω-bisphospholanes was developed. The method involves the replacement of aluminium in aluminacyclopentanes, prepared in situ by catalytic cycloalumination of α-olefins and α,ω-diolefins, by phosphorus atoms on treatment with dichlorophosphines (R'PCl2). Hydrogen peroxide oxidation and treatment with S8 of the synthesized phospholanes and α,ω-bisphospholanes afforded the corresponding 3-alkyl(aryl)-1-alkyl(phenyl)phospholane 1-oxides, 3-alkyl(aryl)-1-alkyl(phenyl)phospholane 1-sulfides, bisphospholane 1,1'-dioxides, and bisphospholane 1,1'-disulfides in nearly quantitative yields. The complexes LMo(CO)5 (L = 3-hexyl-1-phenylphospholane, 3-benzyl-1-methylphospholane, 1,2-bis(1-phenylphospholan-3-yl)ethane, and "],"journal":["Beilstein journal of organic chemistry"],"pagination":["406-12"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4902032"],"repository":["biostudies-literature"],"pubmed_title":["Aluminacyclopentanes in the synthesis of 3-substituted phospholanes and α,ω-bisphospholanes."],"pmcid":["PMC4902032"],"pubmed_authors":["D'yakonov VA","Agliullina RA","Dzhemilev UM","Makhamatkhanova AL","Tyumkina TV","Dilmukhametova LK"],"additional_accession":[]},"is_claimable":false,"name":"Aluminacyclopentanes in the synthesis of 3-substituted phospholanes and α,ω-bisphospholanes.","description":"An efficient one-pot process for the synthesis of 3-substituted phospholanes and α,ω-bisphospholanes was developed. The method involves the replacement of aluminium in aluminacyclopentanes, prepared in situ by catalytic cycloalumination of α-olefins and α,ω-diolefins, by phosphorus atoms on treatment with dichlorophosphines (R'PCl2). Hydrogen peroxide oxidation and treatment with S8 of the synthesized phospholanes and α,ω-bisphospholanes afforded the corresponding 3-alkyl(aryl)-1-alkyl(phenyl)phospholane 1-oxides, 3-alkyl(aryl)-1-alkyl(phenyl)phospholane 1-sulfides, bisphospholane 1,1'-dioxides, and bisphospholane 1,1'-disulfides in nearly quantitative yields. The complexes LMo(CO)5 (L = 3-hexyl-1-phenylphospholane, 3-benzyl-1-methylphospholane, 1,2-bis(1-phenylphospholan-3-yl)ethane, and ","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016","modification":"2025-04-25T19:16:38.824Z","creation":"2019-03-27T02:15:47Z"},"accession":"S-EPMC4902032","cross_references":{"pubmed":["27340436"],"doi":["10.3762/bjoc.12.43"]}}