{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["72(Pt 7)"],"submitter":["Muller TG"],"pubmed_abstract":["Di-μ-thio-cyanato-bis-[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear mol-ecule, the Ag(I) atom is coordinated by two ammine ligands and the S atom of one thio-cyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thio-cyanate anions at longer distances, leading to a dimer with point group symmetry C 2. The distance between the Ag(I) atoms in the dimer is at 3.0927 (6) Å within the range of argentophilic inter-actions. The crystal structure displays N-H⋯N and N-H⋯S hydrogen-bonding inter-actions that build up a three-dimensional network."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["881-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC4992897"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of Ag2(μ-SCN)2(NH3)4."],"pmcid":["PMC4992897"],"pubmed_authors":["Muller TG","Kraus F"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of Ag2(μ-SCN)2(NH3)4.","description":"Di-μ-thio-cyanato-bis-[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear mol-ecule, the Ag(I) atom is coordinated by two ammine ligands and the S atom of one thio-cyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thio-cyanate anions at longer distances, leading to a dimer with point group symmetry C 2. The distance between the Ag(I) atoms in the dimer is at 3.0927 (6) Å within the range of argentophilic inter-actions. The crystal structure displays N-H⋯N and N-H⋯S hydrogen-bonding inter-actions that build up a three-dimensional network.","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Jul","modification":"2025-04-21T15:22:43.611Z","creation":"2019-03-27T02:21:11Z"},"accession":"S-EPMC4992897","cross_references":{"pubmed":["27555922"],"doi":["10.1107/S2056989016008823"]}}