{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["72(Pt 9)"],"submitter":["Wilson-Konderka C"],"pubmed_abstract":["The title solvated complex, [FePd(C<sub>5</sub>H<sub>5</sub>)(C<sub>12</sub>H<sub>13</sub>N<sub>2</sub>S)Cl(C<sub>18</sub>H<sub>15</sub>P)<sub>2</sub>]PF<sub>6</sub>·2CHCl<sub>3</sub>, bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene <i>N</i>-heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh<sub>3</sub>)<sub>4</sub>. The Pd<sup>II</sup> ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom <i>trans</i> to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along ["],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["1330-1334"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5120718"],"repository":["biostudies-literature"],"pubmed_title":["(+)-<i>trans</i>-Chlorido-{2-[(<i>R</i><sub>p</sub>)-2-(methyl-sulfan-yl)ferro-cen-yl]-2,5,6,7-tetra-hydro-pyrrolo-[1,2-<i>c</i>]imidazol-3-yl-idene}bis(tri-phenyl-phosphane-κ<i>P</i>)palladium(II) hexa-fluorido-phosphate di-chloro-form disolvate."],"pmcid":["PMC5120718"],"pubmed_authors":["Lough AJ","Metallinos C","Wilson-Konderka C"],"additional_accession":[]},"is_claimable":false,"name":"(+)-<i>trans</i>-Chlorido-{2-[(<i>R</i><sub>p</sub>)-2-(methyl-sulfan-yl)ferro-cen-yl]-2,5,6,7-tetra-hydro-pyrrolo-[1,2-<i>c</i>]imidazol-3-yl-idene}bis(tri-phenyl-phosphane-κ<i>P</i>)palladium(II) hexa-fluorido-phosphate di-chloro-form disolvate.","description":"The title solvated complex, [FePd(C<sub>5</sub>H<sub>5</sub>)(C<sub>12</sub>H<sub>13</sub>N<sub>2</sub>S)Cl(C<sub>18</sub>H<sub>15</sub>P)<sub>2</sub>]PF<sub>6</sub>·2CHCl<sub>3</sub>, bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene <i>N</i>-heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh<sub>3</sub>)<sub>4</sub>. The Pd<sup>II</sup> ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom <i>trans</i> to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along [","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Sep","modification":"2025-04-27T01:23:27.054Z","creation":"2019-03-27T02:29:38Z"},"accession":"S-EPMC5120718","cross_references":{"pubmed":["27920928"],"doi":["10.1107/S2056989016013190"]}}