biostudies-literatureUnknown72(Pt 9)Wilson-Konderka CThe title solvated complex, [FePd(C₅H₅)(C₁₂H₁₃N₂S)Cl(C₁₈H₁₅P)₂]PF₆·2CHCl₃, bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene <i>N</i>-heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh₃)₄. The Pd^II ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom <i>trans</i> to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along [Acta crystallographica. Section E, Crystallographic communications1330-1334https://www.ebi.ac.uk/biostudies/studies/S-EPMC5120718biostudies-literature(+)-<i>trans</i>-Chlorido-{2-[(<i>R</i>_p)-2-(methyl-sulfan-yl)ferro-cen-yl]-2,5,6,7-tetra-hydro-pyrrolo-[1,2-<i>c</i>]imidazol-3-yl-idene}bis(tri-phenyl-phosphane-κ<i>P</i>)palladium(II) hexa-fluorido-phosphate di-chloro-form disolvate.PMC5120718Lough AJMetallinos CWilson-Konderka Cfalse(+)-<i>trans</i>-Chlorido-{2-[(<i>R</i>_p)-2-(methyl-sulfan-yl)ferro-cen-yl]-2,5,6,7-tetra-hydro-pyrrolo-[1,2-<i>c</i>]imidazol-3-yl-idene}bis(tri-phenyl-phosphane-κ<i>P</i>)palladium(II) hexa-fluorido-phosphate di-chloro-form disolvate.The title solvated complex, [FePd(C₅H₅)(C₁₂H₁₃N₂S)Cl(C₁₈H₁₅P)₂]PF₆·2CHCl₃, bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene <i>N</i>-heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh₃)₄. The Pd^II ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom <i>trans</i> to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along [2016-01-01T00:00:00Z2016 Sep2025-04-27T01:23:27.054Z2019-03-27T02:29:38ZS-EPMC51207182792092810.1107/S2056989016013190