{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["72(Pt 12)"],"submitter":["Al-Najjar N"],"pubmed_abstract":["In the mononuclear title complex, [CuI(C<sub>2</sub>H<sub>3</sub>N)(C<sub>26</sub>H<sub>24</sub>N<sub>2</sub>)], the Cu<sup>I</sup> ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["1845-1847"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5137624"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of (aceto-nitrile-κ<i>N</i>)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')copper(I)."],"pmcid":["PMC5137624"],"pubmed_authors":["Singh K","Al-Najjar N","Solan GA"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of (aceto-nitrile-κ<i>N</i>)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ<sup>2</sup><i>N</i>,<i>N</i>')copper(I).","description":"In the mononuclear title complex, [CuI(C<sub>2</sub>H<sub>3</sub>N)(C<sub>26</sub>H<sub>24</sub>N<sub>2</sub>)], the Cu<sup>I</sup> ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network.","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Dec","modification":"2025-04-26T02:03:41.785Z","creation":"2019-03-27T02:30:48Z"},"accession":"S-EPMC5137624","cross_references":{"pubmed":["27980846"],"doi":["10.1107/S2056989016018685"]}}