<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>72(Pt 12)</volume><submitter>Al-Najjar N</submitter><pubmed_abstract>In the mononuclear title complex, [CuI(C&lt;sub>2&lt;/sub>H&lt;sub>3&lt;/sub>N)(C&lt;sub>26&lt;/sub>H&lt;sub>24&lt;/sub>N&lt;sub>2&lt;/sub>)], the Cu&lt;sup>I&lt;/sup> ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>1845-1847</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC5137624</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of (aceto-nitrile-κ&lt;i>N&lt;/i>)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ&lt;sup>2&lt;/sup>&lt;i>N&lt;/i>,&lt;i>N&lt;/i>')copper(I).</pubmed_title><pmcid>PMC5137624</pmcid><pubmed_authors>Singh K</pubmed_authors><pubmed_authors>Al-Najjar N</pubmed_authors><pubmed_authors>Solan GA</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of (aceto-nitrile-κ&lt;i>N&lt;/i>)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ&lt;sup>2&lt;/sup>&lt;i>N&lt;/i>,&lt;i>N&lt;/i>')copper(I).</name><description>In the mononuclear title complex, [CuI(C&lt;sub>2&lt;/sub>H&lt;sub>3&lt;/sub>N)(C&lt;sub>26&lt;/sub>H&lt;sub>24&lt;/sub>N&lt;sub>2&lt;/sub>)], the Cu&lt;sup>I&lt;/sup> ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network.</description><dates><release>2016-01-01T00:00:00Z</release><publication>2016 Dec</publication><modification>2025-04-26T02:03:41.785Z</modification><creation>2019-03-27T02:30:48Z</creation></dates><accession>S-EPMC5137624</accession><cross_references><pubmed>27980846</pubmed><doi>10.1107/S2056989016018685</doi></cross_references></HashMap>