{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Chakrabarti N"],"funding":["National Institute of General Medical Sciences","NIGMS NIH HHS"],"pagination":["12105-12109"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5142449"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["55(23)"],"pubmed_abstract":["Tris(2-pyridylthio)methane ([Tptm]H) has been employed to synthesize a series of cadmium carbatrane compounds that feature an [N<sub>3</sub>C] coordination environment. Specifically, [Tptm]H reacts with Cd[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> to afford [Tptm]CdN(SiMe<sub>3</sub>)<sub>2</sub>, which thereby provides access to other derivatives. For example, [Tptm]CdN(SiMe<sub>3</sub>)<sub>2</sub> reacts with (i) CO<sub>2</sub> to form {[Tptm]Cd(μ-NCO)}<sub>2</sub> and (ii) Me<sub>3</sub>SiOH and Ph<sub>3</sub>SiOH to form {[κ<sup>3</sup>-Tptm]Cd(μ-OSiMe<sub>3</sub>)}<sub>2</sub> and [Tptm]CdOSiPh<sub>3</sub>, respectively. The siloxide compound {[κ<sup>3</sup>-Tptm]Cd(μ-OSiMe<sub>3</sub>)}<sub>2</sub> reacts with Me<sub>3</sub>SiX (X = Cl, Br, O<sub>2</sub>CMe) to give [Tptm]CdX, wh"],"journal":["Inorganic chemistry"],"pubmed_title":["Cadmium Compounds with an [N<sub>3</sub>C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species."],"pmcid":["PMC5142449"],"funding_grant_id":["R01GM046502","R01 GM046502"],"pubmed_authors":["Chakrabarti N","Ruccolo S","Parkin G"],"additional_accession":[]},"is_claimable":false,"name":"Cadmium Compounds with an [N<sub>3</sub>C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species.","description":"Tris(2-pyridylthio)methane ([Tptm]H) has been employed to synthesize a series of cadmium carbatrane compounds that feature an [N<sub>3</sub>C] coordination environment. Specifically, [Tptm]H reacts with Cd[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> to afford [Tptm]CdN(SiMe<sub>3</sub>)<sub>2</sub>, which thereby provides access to other derivatives. For example, [Tptm]CdN(SiMe<sub>3</sub>)<sub>2</sub> reacts with (i) CO<sub>2</sub> to form {[Tptm]Cd(μ-NCO)}<sub>2</sub> and (ii) Me<sub>3</sub>SiOH and Ph<sub>3</sub>SiOH to form {[κ<sup>3</sup>-Tptm]Cd(μ-OSiMe<sub>3</sub>)}<sub>2</sub> and [Tptm]CdOSiPh<sub>3</sub>, respectively. The siloxide compound {[κ<sup>3</sup>-Tptm]Cd(μ-OSiMe<sub>3</sub>)}<sub>2</sub> reacts with Me<sub>3</sub>SiX (X = Cl, Br, O<sub>2</sub>CMe) to give [Tptm]CdX, wh","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Dec","modification":"2025-04-21T20:23:47.473Z","creation":"2019-03-27T02:30:59Z"},"accession":"S-EPMC5142449","cross_references":{"pubmed":["27934411"],"doi":["10.1021/acs.inorgchem.6b02196"]}}