{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Da Via L"],"funding":["Engineering and Physical Sciences Research Council"],"pagination":["3475-3483"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5396341"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(22)"],"pubmed_abstract":["The visible-light-mediated photo-catalytic selective valorisation of glucose using TiO<sub>2</sub>-supported Ag nanoparticles is shown for the first time. The optimisation of the catalyst composition, substrate-to-catalyst ratio and reaction medium proved that a near total suppression of the mineralisation pathway could be achieved with a selectivity to partial oxidation products and small-chain monosaccharides as high as 98 %. The primary products were determined to be gluconic acid, arabinose, erythrose, glyceraldehyde and formic acid. Under UVA light, the selectivity to organics decreases because of the production of CO<sub>2</sub> from mineralisation. A reaction mechanism is proposed based on an α-scission process combined with the Ruff degradation reaction, which explains the presence"],"journal":["ChemCatChem"],"pubmed_title":["Visible-Light-Controlled Oxidation of Glucose using Titania-Supported Silver Photocatalysts."],"pmcid":["PMC5396341"],"funding_grant_id":["EP/K014773/1","EP/K014714/1"],"pubmed_authors":["Da Via L","Lopez-Sanchez JA","Greeves N","Davies TE","Recchi C"],"additional_accession":[]},"is_claimable":false,"name":"Visible-Light-Controlled Oxidation of Glucose using Titania-Supported Silver Photocatalysts.","description":"The visible-light-mediated photo-catalytic selective valorisation of glucose using TiO<sub>2</sub>-supported Ag nanoparticles is shown for the first time. The optimisation of the catalyst composition, substrate-to-catalyst ratio and reaction medium proved that a near total suppression of the mineralisation pathway could be achieved with a selectivity to partial oxidation products and small-chain monosaccharides as high as 98 %. The primary products were determined to be gluconic acid, arabinose, erythrose, glyceraldehyde and formic acid. Under UVA light, the selectivity to organics decreases because of the production of CO<sub>2</sub> from mineralisation. A reaction mechanism is proposed based on an α-scission process combined with the Ruff degradation reaction, which explains the presence","dates":{"release":"2016-01-01T00:00:00Z","publication":"2016 Nov","modification":"2025-04-26T18:49:14.758Z","creation":"2019-03-27T02:41:34Z"},"accession":"S-EPMC5396341","cross_references":{"pubmed":["28450968"],"doi":["10.1002/cctc.201600775"]}}