{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Dhar D"],"funding":["Division of Chemistry","National Institutes of Health","NIGMS NIH HHS"],"pagination":["1075-1085"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5452261"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(2)"],"pubmed_abstract":["Kinetic studies of the reactions of two previously characterized copper(iii)-hydroxide complexes (LCuOH and <sup>NO<sub>2</sub></sup> LCuOH, where L = <i>N</i>,<i>N</i>'-bis(2,6-diisopropylphenyl)-2,6-pyridine-dicarboxamide and <sup>NO<sub>2</sub></sup> L = <i>N</i>,<i>N</i>'-bis(2,6-diisopropyl-4-nitrophenyl)pyridine-2,6-dicarboxamide) with a series of <i>para</i> substituted phenols (<sup>X</sup>ArOH where X = NMe<sub>2</sub>, OMe, Me, H, Cl, NO<sub>2</sub>, or CF<sub>3</sub>) were performed using low temperature stopped-flow UV-vis spectroscopy. Second-order rate constants (<i>k</i>) were determined from pseudo first-order and stoichiometric experiments, and follow the trends CF<sub>3</sub> < NO<sub>2</sub> < Cl < H < Me < OMe < NMe<sub>2</sub> and LCuOH < <sup>NO<sub>2</sub></sup> LCuO"],"journal":["Chemical science"],"pubmed_title":["Reactivity of the copper(iii)-hydroxide unit with phenols."],"pmcid":["PMC5452261"],"funding_grant_id":["R37 GM047365","CHE-1229400","5R01GM050422","R37GM47365","R01 GM050422"],"pubmed_authors":["Yee GM","Tolman WB","Mayer JM","Markle TF","Dhar D"],"additional_accession":[]},"is_claimable":false,"name":"Reactivity of the copper(iii)-hydroxide unit with phenols.","description":"Kinetic studies of the reactions of two previously characterized copper(iii)-hydroxide complexes (LCuOH and <sup>NO<sub>2</sub></sup> LCuOH, where L = <i>N</i>,<i>N</i>'-bis(2,6-diisopropylphenyl)-2,6-pyridine-dicarboxamide and <sup>NO<sub>2</sub></sup> L = <i>N</i>,<i>N</i>'-bis(2,6-diisopropyl-4-nitrophenyl)pyridine-2,6-dicarboxamide) with a series of <i>para</i> substituted phenols (<sup>X</sup>ArOH where X = NMe<sub>2</sub>, OMe, Me, H, Cl, NO<sub>2</sub>, or CF<sub>3</sub>) were performed using low temperature stopped-flow UV-vis spectroscopy. Second-order rate constants (<i>k</i>) were determined from pseudo first-order and stoichiometric experiments, and follow the trends CF<sub>3</sub> < NO<sub>2</sub> < Cl < H < Me < OMe < NMe<sub>2</sub> and LCuOH < <sup>NO<sub>2</sub></sup> LCuO","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Feb","modification":"2026-05-05T09:48:45.418Z","creation":"2019-03-27T02:46:27Z"},"accession":"S-EPMC5452261","cross_references":{"pubmed":["28572905"],"doi":["10.1039/c6sc03039d"]}}