{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["7(7)"],"submitter":["Spasojevic M"],"pubmed_abstract":["The synthesis of poly(<i>N</i>-isopropylacrylamide)-b-poly(L-lysine) and poly(<i>N</i>- isopropylacrylamide-co-acrylamide)-b-poly(L-lysine) copolymers was accomplished by combining atom transfer radical polymerization (ATRP) and ring opening polymerization (ROP). For this purpose, a di-functional initiator with protected amino group was successfully synthetized. The ATRP of <i>N</i>-isopropylacrylamide yielded narrowly dispersed polymers with consistent high yields (~80%). Lower yields (~50%) were observed when narrowly dispersed random copolymers of <i>N</i>-isopropylacrylamide and acrylamide where synthesized. Amino-terminated poly(<i>N</i>-isopropylacrylamide) and poly(<i>N</i>-isopropylacrylamide- co-acrylamide) were successfully used as macroinitiators for ROP of <i>N</i>₆-carbobenzox"],"journal":["Materials (Basel, Switzerland)"],"pagination":["5305-5326"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5455825"],"repository":["biostudies-literature"],"pubmed_title":["Synthesis and Phase Behavior of Poly(<i>N</i>-isopropylacrylamide)-b- Poly(L-Lysine Hydrochloride) and Poly(<i>N</i>-Isopropylacrylamide- co-Acrylamide)-b-Poly(L-Lysine Hydrochloride)."],"pmcid":["PMC5455825"],"pubmed_authors":["Schouten AJ","Jansen MRPACS","Spasojevic M","de Vos P","Vorenkamp J"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis and Phase Behavior of Poly(<i>N</i>-isopropylacrylamide)-b- Poly(L-Lysine Hydrochloride) and Poly(<i>N</i>-Isopropylacrylamide- co-Acrylamide)-b-Poly(L-Lysine Hydrochloride).","description":"The synthesis of poly(<i>N</i>-isopropylacrylamide)-b-poly(L-lysine) and poly(<i>N</i>- isopropylacrylamide-co-acrylamide)-b-poly(L-lysine) copolymers was accomplished by combining atom transfer radical polymerization (ATRP) and ring opening polymerization (ROP). For this purpose, a di-functional initiator with protected amino group was successfully synthetized. The ATRP of <i>N</i>-isopropylacrylamide yielded narrowly dispersed polymers with consistent high yields (~80%). Lower yields (~50%) were observed when narrowly dispersed random copolymers of <i>N</i>-isopropylacrylamide and acrylamide where synthesized. Amino-terminated poly(<i>N</i>-isopropylacrylamide) and poly(<i>N</i>-isopropylacrylamide- co-acrylamide) were successfully used as macroinitiators for ROP of <i>N</i>₆-carbobenzox","dates":{"release":"2014-01-01T00:00:00Z","publication":"2014 Jul","modification":"2025-04-22T16:41:17.283Z","creation":"2019-03-27T02:46:38Z"},"accession":"S-EPMC5455825","cross_references":{"pubmed":["28788130"],"doi":["10.3390/ma7075305"]}}