biostudies-literatureUnknown7(1)Tonin GDue to its high theoretical specific capacity, the lithium/sulfur battery is one of the most promising candidates for replacing current lithium-ion batteries. In this work, we investigate both chemical and morphological changes in the electrodes during cycling, by coupling operando spatially resolved X-ray diffraction and absorption tomography to characterize Li/S cells under real working conditions. By combining these tools, the state of the active material in the entire cell was correlated with its electrochemical behavior, leading to a deeper understanding of the performance limiting degradation phenomena in Li/S batteries. Highly heterogeneous behavior of lithium stripping/plating was observed in the anode, while the evolution of sulfur distribution in the cathode depth was followed duScientific reports2755https://www.ebi.ac.uk/biostudies/studies/S-EPMC5459854biostudies-literatureMultiscale characterization of a lithium/sulfur battery by coupling operando X-ray tomography and spatially-resolved diffraction.PMC5459854Colin JFBarchasz CDi Michiel MBoutafa LBouchet RTonin GVaughan GAlloin FfalseMultiscale characterization of a lithium/sulfur battery by coupling operando X-ray tomography and spatially-resolved diffraction.Due to its high theoretical specific capacity, the lithium/sulfur battery is one of the most promising candidates for replacing current lithium-ion batteries. In this work, we investigate both chemical and morphological changes in the electrodes during cycling, by coupling operando spatially resolved X-ray diffraction and absorption tomography to characterize Li/S cells under real working conditions. By combining these tools, the state of the active material in the entire cell was correlated with its electrochemical behavior, leading to a deeper understanding of the performance limiting degradation phenomena in Li/S batteries. Highly heterogeneous behavior of lithium stripping/plating was observed in the anode, while the evolution of sulfur distribution in the cathode depth was followed du2017-01-01T00:00:00Z2017 Jun2025-04-04T12:29:20.672Z2019-03-27T02:46:54ZS-EPMC54598542858423710.1038/s41598-017-03004-4