{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["33(22)"],"submitter":["Dral AP"],"funding":["Ministerie van Economische Zaken"],"pubmed_abstract":["It is generally assumed that the hydrothermal stability of organically modified silica networks is promoted by high monomer connectivity, network flexibility, and the presence of hydrophobic groups in the network. In this study a range of organosilica compositions is synthesized to explore the extent to which these factors play a role in the hydrothermal dissolution of these materials. Compositions were synthesized from hexafunctional organically bridged silsesquioxanes (OR<sub>1</sub>)<sub>3</sub>Si-R-Si(OR<sub>1</sub>)<sub>3</sub> (R = -CH<sub>2</sub>-, -C<sub>2</sub>H<sub>4</sub>-, -C<sub>6</sub>H<sub>12</sub>-, -C<sub>8</sub>H<sub>16</sub>-, -p-C<sub>6</sub>H<sub>4</sub>-; R<sub>1</sub> = -CH<sub>3</sub>, -C<sub>2</sub>H<sub>5</sub>), tetrafunctional (OEt)<sub>2</sub>Si(CH<sub>3</sub>)"],"journal":["Langmuir : the ACS journal of surfaces and colloids"],"pagination":["5527-5536"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5465508"],"repository":["biostudies-literature"],"pubmed_title":["Influence of Monomer Connectivity, Network Flexibility, and Hydrophobicity on the Hydrothermal Stability of Organosilicas."],"pmcid":["PMC5465508"],"pubmed_authors":["Ten Elshof JE","Dral AP","Lievens C"],"additional_accession":[]},"is_claimable":false,"name":"Influence of Monomer Connectivity, Network Flexibility, and Hydrophobicity on the Hydrothermal Stability of Organosilicas.","description":"It is generally assumed that the hydrothermal stability of organically modified silica networks is promoted by high monomer connectivity, network flexibility, and the presence of hydrophobic groups in the network. In this study a range of organosilica compositions is synthesized to explore the extent to which these factors play a role in the hydrothermal dissolution of these materials. Compositions were synthesized from hexafunctional organically bridged silsesquioxanes (OR<sub>1</sub>)<sub>3</sub>Si-R-Si(OR<sub>1</sub>)<sub>3</sub> (R = -CH<sub>2</sub>-, -C<sub>2</sub>H<sub>4</sub>-, -C<sub>6</sub>H<sub>12</sub>-, -C<sub>8</sub>H<sub>16</sub>-, -p-C<sub>6</sub>H<sub>4</sub>-; R<sub>1</sub> = -CH<sub>3</sub>, -C<sub>2</sub>H<sub>5</sub>), tetrafunctional (OEt)<sub>2</sub>Si(CH<sub>3</sub>)","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Jun","modification":"2025-06-01T03:33:06.112Z","creation":"2025-06-01T03:33:06.112Z"},"accession":"S-EPMC5465508","cross_references":{"pubmed":["28514155"],"doi":["10.1021/acs.langmuir.7b00971"]}}