{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["73(Pt 7)"],"submitter":["Wu Q"],"pubmed_abstract":["In the title compound, [Co(C<sub>57</sub>H<sub>52</sub>N<sub>6</sub>O<sub>6</sub>)], the central Co<sup>II</sup> atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (<i>C</i><sub>a</sub>), 0.20 (10) (<i>C</i><sub>b</sub>), 0.24 (4) (<i>C</i><sub>m</sub>) and 0.18 (10) Å (<i>C</i><sub>av</sub>), respectively. The axial Co-O bond length is 2.3380 (15) and the average Co-N<sub>p</sub> bond length is 1.968 (5) Å. Intra-molecular N-H⋯O and inter-molecular C-H⋯π inter-actions are observed."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["963-966"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5499269"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of (5-{3-[(1,4,7,10,13-penta-oxa-16-aza-cyclo-octa-decan-16-yl)carbonyl-amino]-phen-yl}-10,15,20-tri-phenyl-porphyrinato)cobalt(II)."],"pmcid":["PMC5499269"],"pubmed_authors":["Li J","Wu Q","He M"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of (5-{3-[(1,4,7,10,13-penta-oxa-16-aza-cyclo-octa-decan-16-yl)carbonyl-amino]-phen-yl}-10,15,20-tri-phenyl-porphyrinato)cobalt(II).","description":"In the title compound, [Co(C<sub>57</sub>H<sub>52</sub>N<sub>6</sub>O<sub>6</sub>)], the central Co<sup>II</sup> atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (<i>C</i><sub>a</sub>), 0.20 (10) (<i>C</i><sub>b</sub>), 0.24 (4) (<i>C</i><sub>m</sub>) and 0.18 (10) Å (<i>C</i><sub>av</sub>), respectively. The axial Co-O bond length is 2.3380 (15) and the average Co-N<sub>p</sub> bond length is 1.968 (5) Å. Intra-molecular N-H⋯O and inter-molecular C-H⋯π inter-actions are observed.","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Jul","modification":"2025-04-04T00:36:26.94Z","creation":"2019-03-27T02:49:36Z"},"accession":"S-EPMC5499269","cross_references":{"pubmed":["28775861"],"doi":["10.1107/S2056989017007745"]}}