{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Castro M"],"funding":["Ministry of Education","European Union","Ministerio de Economía y Competitividad","Ministry of Education (Spain)","Diputación General de Aragón"],"pagination":["731-742"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5601254"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["73(Pt 9)"],"pubmed_abstract":["The preparation and characterization of the <sup>n</sup>Bu<sub>4</sub>N<sup>+</sup> salts of two bis-orotate(2-) complexes of cobalt, namely bis(tetra-n-butylammonium) diaquabis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(II) 1.8-hydrate, (C<sub>16</sub>H<sub>36</sub>N)<sub>2</sub>[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·1.8H<sub>2</sub>O, (1), and tetra-n-butylammonium (2,2'-bipyridine-κ<sup>2</sup>N,N')bis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(III) trihydrate, (C<sub>16</sub>H<sub>36</sub>N)[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)]·3"],"journal":["Acta crystallographica. Section C, Structural chemistry"],"pubmed_title":["A phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (<sup>n</sup>Bu<sub>4</sub>N)[Co(orotate)<sub>2</sub>(bipy)]·3H<sub>2</sub>O."],"pmcid":["PMC5601254"],"funding_grant_id":["MAT2015-68200-C2-1-P","FEDER funds","AP2009-4211","E16 (M4)"],"pubmed_authors":["Al-Kenany NA","Tomas M","Forcen-Vazquez E","Castro M","Guerra P","Falvello LR","Martinez G"],"additional_accession":[]},"is_claimable":false,"name":"A phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (<sup>n</sup>Bu<sub>4</sub>N)[Co(orotate)<sub>2</sub>(bipy)]·3H<sub>2</sub>O.","description":"The preparation and characterization of the <sup>n</sup>Bu<sub>4</sub>N<sup>+</sup> salts of two bis-orotate(2-) complexes of cobalt, namely bis(tetra-n-butylammonium) diaquabis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(II) 1.8-hydrate, (C<sub>16</sub>H<sub>36</sub>N)<sub>2</sub>[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·1.8H<sub>2</sub>O, (1), and tetra-n-butylammonium (2,2'-bipyridine-κ<sup>2</sup>N,N')bis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(III) trihydrate, (C<sub>16</sub>H<sub>36</sub>N)[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)]·3","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Sep","modification":"2025-04-04T14:46:15.379Z","creation":"2019-10-30T08:12:50Z"},"accession":"S-EPMC5601254","cross_references":{"pubmed":["28872072"],"doi":["10.1107/S2053229617010841"]}}