biostudies-literatureCastro MMinistry of EducationEuropean UnionMinisterio de Economía y CompetitividadMinistry of Education (Spain)Diputación General de Aragón731-742https://www.ebi.ac.uk/biostudies/studies/S-EPMC5601254biostudies-literatureUnknown73(Pt 9)The preparation and characterization of the <sup>n</sup>Bu<sub>4</sub>N<sup>+</sup> salts of two bis-orotate(2-) complexes of cobalt, namely bis(tetra-n-butylammonium) diaquabis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(II) 1.8-hydrate, (C<sub>16</sub>H<sub>36</sub>N)<sub>2</sub>[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·1.8H<sub>2</sub>O, (1), and tetra-n-butylammonium (2,2'-bipyridine-κ<sup>2</sup>N,N')bis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(III) trihydrate, (C<sub>16</sub>H<sub>36</sub>N)[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)]·3Acta crystallographica. Section C, Structural chemistryA phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (<sup>n</sup>Bu<sub>4</sub>N)[Co(orotate)<sub>2</sub>(bipy)]·3H<sub>2</sub>O.PMC5601254MAT2015-68200-C2-1-PFEDER fundsAP2009-4211E16 (M4)Al-Kenany NATomas MForcen-Vazquez ECastro MGuerra PFalvello LRMartinez GfalseA phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (<sup>n</sup>Bu<sub>4</sub>N)[Co(orotate)<sub>2</sub>(bipy)]·3H<sub>2</sub>O.The preparation and characterization of the <sup>n</sup>Bu<sub>4</sub>N<sup>+</sup> salts of two bis-orotate(2-) complexes of cobalt, namely bis(tetra-n-butylammonium) diaquabis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(II) 1.8-hydrate, (C<sub>16</sub>H<sub>36</sub>N)<sub>2</sub>[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·1.8H<sub>2</sub>O, (1), and tetra-n-butylammonium (2,2'-bipyridine-κ<sup>2</sup>N,N')bis(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-ide-6-carboxylato-κ<sup>2</sup>N<sup>1</sup>,O<sup>6</sup>)cobalt(III) trihydrate, (C<sub>16</sub>H<sub>36</sub>N)[Co(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)]·32017-01-01T00:00:00Z2017 Sep2025-04-04T14:46:15.379Z2019-10-30T08:12:50ZS-EPMC56012542887207210.1107/S2053229617010841