biostudies-literature00590Chierchia MNational Institute of General Medical SciencesNIGMS NIH HHS11870-11874https://www.ebi.ac.uk/biostudies/studies/S-EPMC5699474biostudies-literatureUnknown56(39)Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.Angewandte Chemie (International ed. in English)Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.PMC5699474GM-118641R01 GM118641R01 GM059417Chierchia MMorken JPLaw C59falseNickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.2017-01-01T00:00:00Z2017 Sep2024-11-14T15:06:41.88Z2019-03-26T23:56:02ZS-EPMC56994742874294410.1002/anie.201706719