{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Abellan G"],"funding":["the Graduate School Molecular Science (GSMS)","Interdisciplinary Center for Molecular Materials","European Research Council","Deutsche Forschungsgemeinschaft","FP7 People: Marie-Curie Actions","DRS Postdoc Fellowship Point-2014 of the NanoScale Focus Area at Freie Universität Berlin","Horizon 2020","Seventh Framework Programme","Friedrich-Alexander-Universität Erlangen-Nürnberg"],"pagination":["15267-15273"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5846882"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["56(48)"],"pubmed_abstract":["Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid-state as well as vapor-phase reactions. By means of a combination of in situ X-ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior."],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals."],"pmcid":["PMC5846882"],"funding_grant_id":["ERC Advanced Grant 742145 B-PhosphoChem","Emerging Talents Initiative (ETI) grant #WS16-17_Nat_04","742145","grant agreement No. 604391 Graphene Flagship","FP7/2013-IEF-627386","FET-OPEN 2D-INK","DFG-SFB 953 "Synthetic Carbon Allotropes", Project A1","DFG-SFB 953 "Synthetic Carbon Allotropes", Project C2"],"pubmed_authors":["Hirsch A","Neiss C","Chacon-Torres JC","Abellan G","Gorling A","Werbach K","Pichler T","Lloret V","Wild S","Hauke F","Peterlik H","Fedi F","Shiozawa H"],"additional_accession":[]},"is_claimable":false,"name":"Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals.","description":"Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid-state as well as vapor-phase reactions. By means of a combination of in situ X-ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Nov","modification":"2025-04-04T09:26:19.527Z","creation":"2019-03-26T23:22:50Z"},"accession":"S-EPMC5846882","cross_references":{"pubmed":["28980764"],"doi":["10.1002/anie.201707462"]}}