{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Sun CY"],"funding":["University Grants Committee","National Science Foundation"],"pagination":["2357-2364"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC5897847"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(8)"],"pubmed_abstract":["Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer (<sup>3</sup>MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a \"solid solution\" environment for easy access to <sup>3</sup>MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composites Pt<sup>II</sup>@MOFs (<b>1-4</b>) with matrix-dependent monomers and oligomer emission properties were obtained. These Pt<sup>II</sup>@MOFs are efficient catalysts for photoinduced dehydrogenation reactions."],"journal":["Chemical science"],"pubmed_title":["Metal-organic framework composites with luminescent pincer platinum(ii) complexes: <sup>3</sup>MMLCT emission and photoinduced dehydrogenation catalysis."],"pmcid":["PMC5897847"],"funding_grant_id":["21471027","AoE/P-03/08","21601032"],"pubmed_authors":["Wang XL","Su ZM","Che CM","To WP","Sun CY","Hung FF"],"additional_accession":[]},"is_claimable":false,"name":"Metal-organic framework composites with luminescent pincer platinum(ii) complexes: <sup>3</sup>MMLCT emission and photoinduced dehydrogenation catalysis.","description":"Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer (<sup>3</sup>MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a \"solid solution\" environment for easy access to <sup>3</sup>MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composites Pt<sup>II</sup>@MOFs (<b>1-4</b>) with matrix-dependent monomers and oligomer emission properties were obtained. These Pt<sup>II</sup>@MOFs are efficient catalysts for photoinduced dehydrogenation reactions.","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Feb","modification":"2025-04-04T13:35:18.807Z","creation":"2019-03-26T23:36:06Z"},"accession":"S-EPMC5897847","cross_references":{"pubmed":["29719708"],"doi":["10.1039/c7sc04528j"]}}