biostudies-literatureSouto MEuropean Research Council2413-2418https://www.ebi.ac.uk/biostudies/studies/S-EPMC5909329biostudies-literatureUnknown9(9)Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(?3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.Chemical scienceA highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst.PMC5909329724681Vieira BJCPalomino MVitorica-Yrezabal IJValencia SSouto MNavalon SGarcia HMinguez Espallargas GSantiago-Portillo AWaerenborgh JCRey FfalseA highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst.Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(?3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.2018-01-01T00:00:00Z2018 Mar2021-02-21T00:53:42Z2019-03-26T23:36:17ZS-EPMC59093292973211610.1039/c7sc04829g