<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>74(Pt 2)</volume><submitter>Saliu KO</submitter><pubmed_abstract>In the title compound, [Lu(C7H7)3(C4H8O)2] (1), the Lu ion is coordinated by three benzyl and two tetra-hydro-furan ligands. Two of the benzyl groups are bonded in a classical η1-fashion through the methyl-ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl-ene C atom, resulting in a modified trigonal-bipyramidal coordination geometry about the Lu center.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>88-90</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC5956313</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of tri-benzyl-bis-(tetra-hydro-furan-κO)lutetium(III).</pubmed_title><pmcid>PMC5956313</pmcid><pubmed_authors>Saliu KO</pubmed_authors><pubmed_authors>McDonald R</pubmed_authors><pubmed_authors>Takats J</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of tri-benzyl-bis-(tetra-hydro-furan-κO)lutetium(III).</name><description>In the title compound, [Lu(C7H7)3(C4H8O)2] (1), the Lu ion is coordinated by three benzyl and two tetra-hydro-furan ligands. Two of the benzyl groups are bonded in a classical η1-fashion through the methyl-ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl-ene C atom, resulting in a modified trigonal-bipyramidal coordination geometry about the Lu center.</description><dates><release>2018-01-01T00:00:00Z</release><publication>2018 Feb</publication><modification>2024-10-18T13:24:44.239Z</modification><creation>2019-03-26T23:39:11Z</creation></dates><accession>S-EPMC5956313</accession><cross_references><pubmed>29850030</pubmed><doi>10.1107/S2056989017018254</doi></cross_references></HashMap>