{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["74(Pt 6)"],"submitter":["Ndoye C"],"funding":["Sonatel Foundation"],"pubmed_abstract":["The binuclear complex, [Sn<sub>2</sub>(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>(C<sub>16</sub>H<sub>10</sub>N<sub>4</sub>O<sub>4</sub>)], contains two Sn<sup>4+</sup> ions, connected by doubly N-deprotonated oxalylbis[(2-oxido-benzyl-idene)hydrazide] ligands, and each Sn<sup>4+</sup> ion is linked to two <i>tert</i>-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C<sub>2</sub>O<sub>2</sub>N environment. The two homologous parts of the doubly deprotonated ligand are located in <i>trans</i> positions with respect to the C-C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C-O and C-N bond lengths. The thre"],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["799-802"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6002830"],"repository":["biostudies-literature"],"pubmed_title":["Crystal structure of (μ-<i>trans</i>-1,2-bis-{2-[(2-oxido-phen-yl)methyl-idene]hydrazin-1-yl-idene}ethane-1,2-diolato-κ<sup>3</sup><i>O</i>,<i>O</i>',<i>N</i>)bis-[di-<i>tert</i>-butyl-tin(IV)]."],"pmcid":["PMC6002830"],"pubmed_authors":["Gautier R","Diallo W","Gaye M","Ndoye C","Diouf O","Barry AH"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of (μ-<i>trans</i>-1,2-bis-{2-[(2-oxido-phen-yl)methyl-idene]hydrazin-1-yl-idene}ethane-1,2-diolato-κ<sup>3</sup><i>O</i>,<i>O</i>',<i>N</i>)bis-[di-<i>tert</i>-butyl-tin(IV)].","description":"The binuclear complex, [Sn<sub>2</sub>(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>(C<sub>16</sub>H<sub>10</sub>N<sub>4</sub>O<sub>4</sub>)], contains two Sn<sup>4+</sup> ions, connected by doubly N-deprotonated oxalylbis[(2-oxido-benzyl-idene)hydrazide] ligands, and each Sn<sup>4+</sup> ion is linked to two <i>tert</i>-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C<sub>2</sub>O<sub>2</sub>N environment. The two homologous parts of the doubly deprotonated ligand are located in <i>trans</i> positions with respect to the C-C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C-O and C-N bond lengths. The thre","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Jun","modification":"2026-07-08T03:17:12.258Z","creation":"2019-03-26T23:43:33Z"},"accession":"S-EPMC6002830","cross_references":{"pubmed":["29951233"],"doi":["10.1107/S2056989018007077"]}}