biostudies-literatureUnknown74(Pt 6)Ndoye CSonatel FoundationThe binuclear complex, [Sn₂(C₄H₉)₄(C₁₆H₁₀N₄O₄)], contains two Sn⁴⁺ ions, connected by doubly N-deprotonated oxalylbis[(2-oxido-benzyl-idene)hydrazide] ligands, and each Sn⁴⁺ ion is linked to two <i>tert</i>-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C₂O₂N environment. The two homologous parts of the doubly deprotonated ligand are located in <i>trans</i> positions with respect to the C-C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C-O and C-N bond lengths. The threActa crystallographica. Section E, Crystallographic communications799-802https://www.ebi.ac.uk/biostudies/studies/S-EPMC6002830biostudies-literatureCrystal structure of (μ-<i>trans</i>-1,2-bis-{2-[(2-oxido-phen-yl)methyl-idene]hydrazin-1-yl-idene}ethane-1,2-diolato-κ³<i>O</i>,<i>O</i>',<i>N</i>)bis-[di-<i>tert</i>-butyl-tin(IV)].PMC6002830Gautier RDiallo WGaye MNdoye CDiouf OBarry AHfalseCrystal structure of (μ-<i>trans</i>-1,2-bis-{2-[(2-oxido-phen-yl)methyl-idene]hydrazin-1-yl-idene}ethane-1,2-diolato-κ³<i>O</i>,<i>O</i>',<i>N</i>)bis-[di-<i>tert</i>-butyl-tin(IV)].The binuclear complex, [Sn₂(C₄H₉)₄(C₁₆H₁₀N₄O₄)], contains two Sn⁴⁺ ions, connected by doubly N-deprotonated oxalylbis[(2-oxido-benzyl-idene)hydrazide] ligands, and each Sn⁴⁺ ion is linked to two <i>tert</i>-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C₂O₂N environment. The two homologous parts of the doubly deprotonated ligand are located in <i>trans</i> positions with respect to the C-C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C-O and C-N bond lengths. The thre2018-01-01T00:00:00Z2018 Jun2026-07-08T03:17:12.258Z2019-03-26T23:43:33ZS-EPMC60028302995123310.1107/S2056989018007077