<HashMap><database>biostudies-literature</database><scores/><additional><submitter>Curland S</submitter><funding>Harold Perlman Family</funding><funding>Israeli Science Foundation</funding><funding>Minerva Foundation</funding><pagination>776-779</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC6002834</full_dataset_link><repository>biostudies-literature</repository><omics_type>Unknown</omics_type><volume>74(Pt 6)</volume><pubmed_abstract>A new polymorph of (2&lt;i>S&lt;/i>,3&lt;i>S&lt;/i>)-2-amino-3-methyl-penta-noic acid, l-isoleucine C&lt;sub>6&lt;/sub>H&lt;sub>13&lt;/sub>NO&lt;sub>2&lt;/sub>, crystallizes in the monoclinic space group &lt;i>P&lt;/i>2&lt;sub>1&lt;/sub> with four independent mol-ecules in the asymmetric unit. The mol-ecules are &lt;i>zwitterions&lt;/i>. In the crystal, N-H⋯O hydrogen bonds link two pairs of independent mol-ecules and their symmetry-related counterparts to form two types of layers stacked in an &lt;i>anti-parallel&lt;/i> manner parallel to (001). The hydro-phobic aliphatic isopropyl groups protrude from these layers.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pubmed_title>Crystal structure of a new polymorph of (2&lt;i>S&lt;/i>,3&lt;i>S&lt;/i>)-2-amino-3-methyl-penta-noic acid.</pubmed_title><pmcid>PMC6002834</pmcid><funding_grant_id>546/17</funding_grant_id><pubmed_authors>Curland S</pubmed_authors><pubmed_authors>Diskin-Posner Y</pubmed_authors><pubmed_authors>Meirzadeh E</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of a new polymorph of (2&lt;i>S&lt;/i>,3&lt;i>S&lt;/i>)-2-amino-3-methyl-penta-noic acid.</name><description>A new polymorph of (2&lt;i>S&lt;/i>,3&lt;i>S&lt;/i>)-2-amino-3-methyl-penta-noic acid, l-isoleucine C&lt;sub>6&lt;/sub>H&lt;sub>13&lt;/sub>NO&lt;sub>2&lt;/sub>, crystallizes in the monoclinic space group &lt;i>P&lt;/i>2&lt;sub>1&lt;/sub> with four independent mol-ecules in the asymmetric unit. The mol-ecules are &lt;i>zwitterions&lt;/i>. In the crystal, N-H⋯O hydrogen bonds link two pairs of independent mol-ecules and their symmetry-related counterparts to form two types of layers stacked in an &lt;i>anti-parallel&lt;/i> manner parallel to (001). The hydro-phobic aliphatic isopropyl groups protrude from these layers.</description><dates><release>2018-01-01T00:00:00Z</release><publication>2018 Jun</publication><modification>2026-07-08T03:17:35.453Z</modification><creation>2019-03-26T23:43:33Z</creation></dates><accession>S-EPMC6002834</accession><cross_references><pubmed>29951228</pubmed><doi>10.1107/S2056989018006126</doi></cross_references></HashMap>