{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ru LJ"],"funding":["National Natural Science Foundation of China"],"pagination":["E1609"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6099668"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["23(7)"],"pubmed_abstract":["A self-assembled ZnII-NdIII heterohexanuclear coordination compound [Zn₄Nd₂(L)₄(bdc)₂]·2NO₃ based on a hexadentate Salamo-like chelating ligand (H₂L = 1,2-bis(3-methoxysalicylideneaminooxy)ethane]) and H₂bdc (H₂bdc = terephthalic acid) has been synthesized and characterized by elemental analyses, IR and UV/Vis spectra, and X-ray crystallography. Two crystallographically equivalent [Zn₂Nd(L)₂] moieties lie in the inversion center linked by two (bdc)2- ligands leading to a heterohexanuclear dimer in which the carboxylato group bridges the ZnII and NdIII atoms. The heteropolynuclear 3d-4f coordination compound includes four ZnII atoms, two NdIII atoms, four completely deprotonated (L)2- units, two fully deprotonated (bdc)2- units, and two crystalling nitrate ions. All of the ZnII atoms in the"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["A Self-Assembled ZnII-NdIII Heterohexanuclear Dimer Based on a Hexadentate N₂O₄-Type Ligand and Terephthalic Acid: Synthesis, Structure, and Fluorescence Properties."],"pmcid":["PMC6099668"],"funding_grant_id":["21761018"],"pubmed_authors":["Ru LJ","Gao L","Guo WT","Ma JC","Dong WK"],"additional_accession":[]},"is_claimable":false,"name":"A Self-Assembled ZnII-NdIII Heterohexanuclear Dimer Based on a Hexadentate N₂O₄-Type Ligand and Terephthalic Acid: Synthesis, Structure, and Fluorescence Properties.","description":"A self-assembled ZnII-NdIII heterohexanuclear coordination compound [Zn₄Nd₂(L)₄(bdc)₂]·2NO₃ based on a hexadentate Salamo-like chelating ligand (H₂L = 1,2-bis(3-methoxysalicylideneaminooxy)ethane]) and H₂bdc (H₂bdc = terephthalic acid) has been synthesized and characterized by elemental analyses, IR and UV/Vis spectra, and X-ray crystallography. Two crystallographically equivalent [Zn₂Nd(L)₂] moieties lie in the inversion center linked by two (bdc)2- ligands leading to a heterohexanuclear dimer in which the carboxylato group bridges the ZnII and NdIII atoms. The heteropolynuclear 3d-4f coordination compound includes four ZnII atoms, two NdIII atoms, four completely deprotonated (L)2- units, two fully deprotonated (bdc)2- units, and two crystalling nitrate ions. All of the ZnII atoms in the","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Jul","modification":"2025-06-01T03:30:08.434Z","creation":"2025-06-01T03:30:08.434Z"},"accession":"S-EPMC6099668","cross_references":{"pubmed":["30004442"],"doi":["10.3390/molecules23071609"]}}