{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["23(7)"],"submitter":["Xue X"],"pubmed_abstract":["Reactions between a N?O? macrocyclic ligand (L¹) and several Zn(II) salts (trifluoromethane sulfonate, <i>p</i>-toluenesulfonate, acetate, benzoate, <i>o</i>-, <i>m</i>- or <i>p</i>-hydroxybenzoate) led to the formation of seven complexes, [Zn?L¹ (DMSO)?](OSO?CF?)? (<b>1</b>), [Zn?(<i>p</i>-OSO?PhCH?)?L¹] (<b>2</b>), [Zn?(OCOCH?)?L¹] (<b>3</b>), [Zn?(OCOPh)?L¹] (<b>4</b>), [Zn?(<i>o</i>-OCOPhOH)?L¹] (<b>5</b>), [Zn?(<i>m</i>-OCOPhOH)? L¹] (<b>6</b>) and [Zn?(<i>p</i>-OCOPhOH)? L¹] (<b>7</b>), which were characterized by elemental analysis, ¹H-NMR, <sup>13</sup>C-NMR, IR, fluorescence spectroscopies and single crystal X-ray diffraction. In <b>1</b>, the Zn atom is pentacoordinated with a N?O? irregular trigonal bipyramidal coordination environment, like the geometries in compounds <b>3</b>?<b>7</b>, whereas in structure <b>2</b> the metal atom is envisaged as possessing a distorted N?O? octahedronal environment. All the compounds show interesting photoluminescent properties in solid states and solutions in DMF and DMSO, which are reported along with their TG-DTA thermal decomposition processes, UV-vis absorption spectroscopy and fluorescence quantum yields in DMF and DMSO."],"journal":["Molecules (Basel, Switzerland)"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6100202"],"repository":["biostudies-literature"],"pubmed_title":["Study on the Photoluminescent and Thermal Properties of Zinc Complexes with a N?O? Macrocyclic Ligand."],"pmcid":["PMC6100202"],"pubmed_authors":["Mai F","Li J","Wang Q","Huang Y","Liang X","Ma Z","Zhou Y","Yang D","Xue X"],"additional_accession":[]},"is_claimable":false,"name":"Study on the Photoluminescent and Thermal Properties of Zinc Complexes with a N?O? Macrocyclic Ligand.","description":"Reactions between a N?O? macrocyclic ligand (L¹) and several Zn(II) salts (trifluoromethane sulfonate, <i>p</i>-toluenesulfonate, acetate, benzoate, <i>o</i>-, <i>m</i>- or <i>p</i>-hydroxybenzoate) led to the formation of seven complexes, [Zn?L¹ (DMSO)?](OSO?CF?)? (<b>1</b>), [Zn?(<i>p</i>-OSO?PhCH?)?L¹] (<b>2</b>), [Zn?(OCOCH?)?L¹] (<b>3</b>), [Zn?(OCOPh)?L¹] (<b>4</b>), [Zn?(<i>o</i>-OCOPhOH)?L¹] (<b>5</b>), [Zn?(<i>m</i>-OCOPhOH)? L¹] (<b>6</b>) and [Zn?(<i>p</i>-OCOPhOH)? L¹] (<b>7</b>), which were characterized by elemental analysis, ¹H-NMR, <sup>13</sup>C-NMR, IR, fluorescence spectroscopies and single crystal X-ray diffraction. In <b>1</b>, the Zn atom is pentacoordinated with a N?O? irregular trigonal bipyramidal coordination environment, like the geometries in compounds <b>3</b>?<b>7</b>, whereas in structure <b>2</b> the metal atom is envisaged as possessing a distorted N?O? octahedronal environment. All the compounds show interesting photoluminescent properties in solid states and solutions in DMF and DMSO, which are reported along with their TG-DTA thermal decomposition processes, UV-vis absorption spectroscopy and fluorescence quantum yields in DMF and DMSO.","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Jul","modification":"2021-02-20T19:33:45Z","creation":"2019-03-27T00:06:40Z"},"accession":"S-EPMC6100202","cross_references":{"pubmed":["30012984"],"doi":["10.3390/molecules23071735"]}}