{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Pereira MM"],"funding":["Petrobras","Conselho Nacional de Desenvolvimento Científico e Tecnológico","Paul Scherrer Institut","Fonds National de la Recherche Luxembourg"],"pagination":["6532-6539"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6115686"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(31)"],"pubmed_abstract":["A family of Al-rich ZSM-5 zeolites with Si/Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of un-expected Al-enriched ZSM-5 structures, hence allowing to cross the frontier of Si/Al lower limit. In addition, these Al-rich ZSM-5 zeolites demonstrated high catalytic activity in <i>n</i>-hexane cracking and methanol conversion into hydrocarbons, being in line with the presence of numerous Brønsted acid sites."],"journal":["Chemical science"],"pubmed_title":["Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si/Al lower limit."],"pmcid":["PMC6115686"],"funding_grant_id":["5898454","400508/2013-3"],"pubmed_authors":["Gomes ES","Silva AV","Laugel G","Losch P","Chizallet C","Pinar AB","Willinger MG","Louis B","Pereira MM","Shanmugam S"],"additional_accession":[]},"is_claimable":false,"name":"Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si/Al lower limit.","description":"A family of Al-rich ZSM-5 zeolites with Si/Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of un-expected Al-enriched ZSM-5 structures, hence allowing to cross the frontier of Si/Al lower limit. In addition, these Al-rich ZSM-5 zeolites demonstrated high catalytic activity in <i>n</i>-hexane cracking and methanol conversion into hydrocarbons, being in line with the presence of numerous Brønsted acid sites.","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Aug","modification":"2025-04-22T12:52:41.101Z","creation":"2019-03-27T00:01:47Z"},"accession":"S-EPMC6115686","cross_references":{"pubmed":["30310584"],"doi":["10.1039/c8sc01675e"]}}