<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>74(Pt 12)</volume><submitter>Kamaal S</submitter><funding>University Grants Commission</funding><funding>National Taras Shevchenko University, Ukraine</funding><pubmed_abstract>In the crystal of the title compound, C15H13NO4·CH3OH, the Schiff base mol-ecule exists in the zwitterionic form; an intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular structure. The benzene rings are nearly co-planar, subtending a dihedral angle of 5.34 (2)°. In the crystal, classical O-H⋯O and weak C-H⋯O hydrogen bonds link the Schiff base mol-ecules and methanol solvent mol-ecules into a three-dimensional supra-molecular architecture. The crystal studied was refined as an inversion twin.</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>1847-1850</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC6281083</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of 4-[(3-meth-oxy-2-oxidobenzyl-idene)azaniumyl]-benzoic acid methanol monosolvate.</pubmed_title><pmcid>PMC6281083</pmcid><pubmed_authors>Kamaal S</pubmed_authors><pubmed_authors>Faizi MSH</pubmed_authors><pubmed_authors>Ali A</pubmed_authors><pubmed_authors>Iskenderov T</pubmed_authors><pubmed_authors>Ahmad M</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of 4-[(3-meth-oxy-2-oxidobenzyl-idene)azaniumyl]-benzoic acid methanol monosolvate.</name><description>In the crystal of the title compound, C15H13NO4·CH3OH, the Schiff base mol-ecule exists in the zwitterionic form; an intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular structure. The benzene rings are nearly co-planar, subtending a dihedral angle of 5.34 (2)°. In the crystal, classical O-H⋯O and weak C-H⋯O hydrogen bonds link the Schiff base mol-ecules and methanol solvent mol-ecules into a three-dimensional supra-molecular architecture. The crystal studied was refined as an inversion twin.</description><dates><release>2018-01-01T00:00:00Z</release><publication>2018 Dec</publication><modification>2025-04-05T00:31:36.355Z</modification><creation>2019-03-27T00:13:26Z</creation></dates><accession>S-EPMC6281083</accession><cross_references><pubmed>30574386</pubmed><doi>10.1107/S2056989018016262</doi></cross_references></HashMap>