{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wellm C"],"funding":["Deutsche Forschungsgemeinschaft"],"pagination":["1899-1902"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6281104"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["74(Pt 12)"],"pubmed_abstract":["The asymmetric unit of the title compound, [Mn(NCS)2(C12H9NO)4], consists of one MnII cation located on a centre of inversion, one thio-cyanate anion and two 4-benzoyl-pyridine co-ligands. The MnII cation is octa-hedrally coordinated by two terminally N-bonded anionic ligands and four N-bonded 4-benzoyl-pyridine co-ligands within a slightly distorted octa-hedron. Individual complexes are linked by inter-molecular C-H⋯O hydrogen-bonding inter-actions into chains running along the c-axis direction. Simultaneous thermogravimetry and differential scanning calorimetry measurements reveal a decomposition in two separate steps, in each of which two co-ligands are removed. The compound obtained after the first step has the composition [Mn(NCS)2(C12H9NO)2] and is of unknown structure, before in the second step decomposition into [Mn(NCS)2] is observed. Magnetic susceptibility measurements show the MnII cations to be in the high-spin state, and that weak anti-ferromagnetic inter-actions between the complexes are present."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pubmed_title":["Tetra-kis(4-benzoyl-pyridine-κN)bis-(iso-thio-cyanato-κN)manganese(II)."],"pmcid":["PMC6281104"],"funding_grant_id":["NA 720/6--1"],"pubmed_authors":["Nather C","Wellm C"],"additional_accession":[]},"is_claimable":false,"name":"Tetra-kis(4-benzoyl-pyridine-κN)bis-(iso-thio-cyanato-κN)manganese(II).","description":"The asymmetric unit of the title compound, [Mn(NCS)2(C12H9NO)4], consists of one MnII cation located on a centre of inversion, one thio-cyanate anion and two 4-benzoyl-pyridine co-ligands. The MnII cation is octa-hedrally coordinated by two terminally N-bonded anionic ligands and four N-bonded 4-benzoyl-pyridine co-ligands within a slightly distorted octa-hedron. Individual complexes are linked by inter-molecular C-H⋯O hydrogen-bonding inter-actions into chains running along the c-axis direction. Simultaneous thermogravimetry and differential scanning calorimetry measurements reveal a decomposition in two separate steps, in each of which two co-ligands are removed. The compound obtained after the first step has the composition [Mn(NCS)2(C12H9NO)2] and is of unknown structure, before in the second step decomposition into [Mn(NCS)2] is observed. Magnetic susceptibility measurements show the MnII cations to be in the high-spin state, and that weak anti-ferromagnetic inter-actions between the complexes are present.","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018 Dec","modification":"2025-04-05T00:31:43.163Z","creation":"2019-03-27T00:13:26Z"},"accession":"S-EPMC6281104","cross_references":{"pubmed":["30574397"],"doi":["10.1107/S2056989018016432"]}}