{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Chen MT"],"funding":["Ministry of Science and Technology, Taiwan"],"pagination":["615"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6328485"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["6"],"pubmed_abstract":["In this work, zinc complexes containing amidopyridinate ligands substituted with different pendant arms have been described. Treatment of ligand precursors with ZnEt<sub>2</sub> at a 1:1 ratio in THF yields zinc ethyl complexes (PyN C 1 Py   )<sub>2</sub>(ZnEt)<sub>2</sub> (<b>1</b>) and (PyN C 2 NMe 2   )<sub>2</sub>(ZnEt)<sub>2</sub> (<b>2</b>), respectively. Complexes <b>1</b> and <b>2</b> show the same geometry as a distorted tetrahedron, but adopt different coordination behaviors supported by the ligands. Complex <b>1</b> represents a rare and a non-centrosymmetric mode, which the amido group bridges two zinc centers to form a six-membered ring. However, complex <b>2</b> shows a centrosymmetric mode, which the pyridine group links to the zinc centers to form an eight-membered ring. Re"],"journal":["Frontiers in chemistry"],"pubmed_title":["Diverse Coordinative Zinc Complexes Containing Amido-Pyridinate Ligands: Structural and Catalytic Studies."],"pmcid":["PMC6328485"],"funding_grant_id":["106-2113-M-126-001-MY2","MOST 106-2113-M-005-016"],"pubmed_authors":["Chen MT","Li GL","Chen CT","Chen YY"],"additional_accession":[]},"is_claimable":false,"name":"Diverse Coordinative Zinc Complexes Containing Amido-Pyridinate Ligands: Structural and Catalytic Studies.","description":"In this work, zinc complexes containing amidopyridinate ligands substituted with different pendant arms have been described. Treatment of ligand precursors with ZnEt<sub>2</sub> at a 1:1 ratio in THF yields zinc ethyl complexes (PyN C 1 Py   )<sub>2</sub>(ZnEt)<sub>2</sub> (<b>1</b>) and (PyN C 2 NMe 2   )<sub>2</sub>(ZnEt)<sub>2</sub> (<b>2</b>), respectively. Complexes <b>1</b> and <b>2</b> show the same geometry as a distorted tetrahedron, but adopt different coordination behaviors supported by the ligands. Complex <b>1</b> represents a rare and a non-centrosymmetric mode, which the amido group bridges two zinc centers to form a six-membered ring. However, complex <b>2</b> shows a centrosymmetric mode, which the pyridine group links to the zinc centers to form an eight-membered ring. Re","dates":{"release":"2018-01-01T00:00:00Z","publication":"2018","modification":"2025-04-04T10:13:14.689Z","creation":"2019-03-26T22:37:48Z"},"accession":"S-EPMC6328485","cross_references":{"pubmed":["30662891"],"doi":["10.3389/fchem.2018.00615"]}}