{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Shen W"],"funding":["National Natural Science Foundation of China"],"pagination":["829-836"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6345353"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(3)"],"pubmed_abstract":["The successful isolation and unambiguous crystallographic assignment of a series of lutetium-containing endohedral metallofullerenes (EMFs), Lu<sub>2</sub>C<sub>2<i>n</i></sub> (2<i>n</i> = 76, 78, 80, 84, 86, 88, 90), reveal an unrecognized decisive effect of the cage size on the configuration of the encapsulated clusters. The molecular structures of these compounds are unambiguously assigned as Lu<sub>2</sub>@<i>T</i> <sub>d</sub>(2)-C<sub>76</sub>, Lu<sub>2</sub>@<i>D</i> <sub>3h</sub>(5)-C<sub>78</sub>, Lu<sub>2</sub>@<i>C</i> <sub>2v</sub>(5)-C<sub>80</sub>, Lu<sub>2</sub>@<i>C</i> <sub>2v</sub>(7)-C<sub>84</sub>, Lu<sub>2</sub>@<i>C</i> <sub>s</sub>(8)-C<sub>86</sub>, Lu<sub>2</sub>@<i>C</i> <sub>s</sub>(15)-C<sub>86</sub>, Lu<sub>2</sub>@<i>C</i> <sub>1</sub>(26)-C<sub>88</sub>, Lu<"],"journal":["Chemical science"],"pubmed_title":["Crystallographic characterization of Lu<sub>2</sub>C<sub>2<i>n</i></sub> (2<i>n</i> = 76-90): cluster selection by cage size."],"pmcid":["PMC6345353"],"funding_grant_id":["51472095","51602097","51672093","51602112","21171061"],"pubmed_authors":["Hu S","Bao L","Yang L","Xie Y","Lu X","Jin P","Shen W","Akasaka T"],"additional_accession":[]},"is_claimable":false,"name":"Crystallographic characterization of Lu<sub>2</sub>C<sub>2<i>n</i></sub> (2<i>n</i> = 76-90): cluster selection by cage size.","description":"The successful isolation and unambiguous crystallographic assignment of a series of lutetium-containing endohedral metallofullerenes (EMFs), Lu<sub>2</sub>C<sub>2<i>n</i></sub> (2<i>n</i> = 76, 78, 80, 84, 86, 88, 90), reveal an unrecognized decisive effect of the cage size on the configuration of the encapsulated clusters. The molecular structures of these compounds are unambiguously assigned as Lu<sub>2</sub>@<i>T</i> <sub>d</sub>(2)-C<sub>76</sub>, Lu<sub>2</sub>@<i>D</i> <sub>3h</sub>(5)-C<sub>78</sub>, Lu<sub>2</sub>@<i>C</i> <sub>2v</sub>(5)-C<sub>80</sub>, Lu<sub>2</sub>@<i>C</i> <sub>2v</sub>(7)-C<sub>84</sub>, Lu<sub>2</sub>@<i>C</i> <sub>s</sub>(8)-C<sub>86</sub>, Lu<sub>2</sub>@<i>C</i> <sub>s</sub>(15)-C<sub>86</sub>, Lu<sub>2</sub>@<i>C</i> <sub>1</sub>(26)-C<sub>88</sub>, Lu<","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jan","modification":"2025-04-04T11:59:24.326Z","creation":"2019-03-26T22:55:11Z"},"accession":"S-EPMC6345353","cross_references":{"pubmed":["30774877"],"doi":["10.1039/c8sc03886d"]}}