{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Kadota K"],"funding":["Strategic International Collaborative Research Program","Adaptable and Seamless Technology Transfer Program through Target-Driven R and D","Japan Society for the Promotion of Science"],"pagination":["6193-6198"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6585883"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(24)"],"pubmed_abstract":["Control of the reactivity of hydride (H<sup>-</sup>) in crystal structures has been a challenge because of its strong electron-donating ability and reactivity with protic species. For metal borohydrides, the dehydrogenation activity and air stability are in a trade-off, and control of the reactivity of BH<sub>4</sub> <sup>-</sup> has been demanded. For this purpose, we synthesize a series of BH<sub>4</sub> <sup>-</sup>-based coordination polymers/metal-organic frameworks. The reactivity of BH<sub>4</sub> <sup>-</sup> in the structures is regulated by coordination geometry and neighboring ligands, and one of the compounds [Zn(BH<sub>4</sub>)<sub>2</sub>(dipyridylpropane)] exhibits both high dehydrogenation reactivity (1.4 wt% at 179 °C) and high air stability (50 RH% at 25 °C, 7 days). Sing"],"journal":["Chemical science"],"pubmed_title":["Borohydride-containing coordination polymers: synthesis, air stability and dehydrogenation."],"pmcid":["PMC6585883"],"funding_grant_id":["Molecular Technology","JP18H02032"],"pubmed_authors":["Horike S","Kadota K","Nishiyama Y","Sivaniah E","Kitagawa S","Duong NT"],"additional_accession":[]},"is_claimable":false,"name":"Borohydride-containing coordination polymers: synthesis, air stability and dehydrogenation.","description":"Control of the reactivity of hydride (H<sup>-</sup>) in crystal structures has been a challenge because of its strong electron-donating ability and reactivity with protic species. For metal borohydrides, the dehydrogenation activity and air stability are in a trade-off, and control of the reactivity of BH<sub>4</sub> <sup>-</sup> has been demanded. For this purpose, we synthesize a series of BH<sub>4</sub> <sup>-</sup>-based coordination polymers/metal-organic frameworks. The reactivity of BH<sub>4</sub> <sup>-</sup> in the structures is regulated by coordination geometry and neighboring ligands, and one of the compounds [Zn(BH<sub>4</sub>)<sub>2</sub>(dipyridylpropane)] exhibits both high dehydrogenation reactivity (1.4 wt% at 179 °C) and high air stability (50 RH% at 25 °C, 7 days). Sing","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jun","modification":"2026-05-06T20:57:33.967Z","creation":"2019-08-02T07:00:38Z"},"accession":"S-EPMC6585883","cross_references":{"pubmed":["31360426"],"doi":["10.1039/c9sc00731h"]}}