biostudies-literature00510Shen GFundamental Research Funds for the Central Universities in ChinaNational Natural Science Foundation of China1102-1109https://www.ebi.ac.uk/biostudies/studies/S-EPMC6641499biostudies-literatureUnknown3(1)The preparation of quantum dot (QD)-sensitized photoanodes, especially the deposition of QDs on TiO₂ matrix, is usually a time-extensive and performance-determinant step in the construction of QD-sensitized solar cells (QDSCs). Herein, a transformative approach for immobilizing QD on the TiO₂ matrix was developed by simply mixing the as-prepared oil-soluble QDs with TiO₂ P25 particles suspension for a period as short as half a minute. The solar paint was prepared by adding the TiO₂/QD composite in a binder solution under ultrasonication. The QD-sensitized photoanodes were then obtained by simply brushing the solar paint on a fluorine-doped tin oxide substrate followed by a low-temperature annealing at ambient atmosphere. Sandwich-structured complete QDSCs were assembled with the use of Cu₂S/brass as counter electrode and polysulfide redox couple as an electrolyte. The photovoltaic performance of the resulting Zn-Cu-In-Se (ZCISe) QDSCs was evaluated after primary optimization of the QD/TiO₂ ratio as well as the thicknesses of photoanode films. In this proof of concept with a simple solar paint approach for photoanode films, an average power conversion efficiency of 4.13% (<i>J</i> _sc = 11.11 mA/cm², <i>V</i> _oc = 0.590 V, fill factor = 0.631) was obtained under standard irradiation condition. This facile solar paint approach offers a simple and convenient approach for QD-sensitized photoanodes in the construction of QDSCs.ACS omegaSolar Paint from TiO₂ Particles Supported Quantum Dots for Photoanodes in Quantum Dot-Sensitized Solar Cells.PMC6641499517320049143310621703071Pan ZZhong XDu ZDu JShen G51falseSolar Paint from TiO₂ Particles Supported Quantum Dots for Photoanodes in Quantum Dot-Sensitized Solar Cells.The preparation of quantum dot (QD)-sensitized photoanodes, especially the deposition of QDs on TiO₂ matrix, is usually a time-extensive and performance-determinant step in the construction of QD-sensitized solar cells (QDSCs). Herein, a transformative approach for immobilizing QD on the TiO₂ matrix was developed by simply mixing the as-prepared oil-soluble QDs with TiO₂ P25 particles suspension for a period as short as half a minute. The solar paint was prepared by adding the TiO₂/QD composite in a binder solution under ultrasonication. The QD-sensitized photoanodes were then obtained by simply brushing the solar paint on a fluorine-doped tin oxide substrate followed by a low-temperature annealing at ambient atmosphere. Sandwich-structured complete QDSCs were assembled with the use of Cu₂S/brass as counter electrode and polysulfide redox couple as an electrolyte. The photovoltaic performance of the resulting Zn-Cu-In-Se (ZCISe) QDSCs was evaluated after primary optimization of the QD/TiO₂ ratio as well as the thicknesses of photoanode films. In this proof of concept with a simple solar paint approach for photoanode films, an average power conversion efficiency of 4.13% (<i>J</i> _sc = 11.11 mA/cm², <i>V</i> _oc = 0.590 V, fill factor = 0.631) was obtained under standard irradiation condition. This facile solar paint approach offers a simple and convenient approach for QD-sensitized photoanodes in the construction of QDSCs.2018-01-01T00:00:00Z2018 Jan2024-02-15T04:15:39.812Z2019-08-31T07:03:09ZS-EPMC66414993145795210.1021/acsomega.7b01761