{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Botubol-Ares JM"],"funding":["Ministerio de Econom?a y Competitividad"],"pagination":["3083-3090"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6641598"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["2(7)"],"pubmed_abstract":["A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using <i>tert</i>-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed."],"journal":["ACS omega"],"pubmed_title":["Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism."],"pmcid":["PMC6641598"],"funding_grant_id":["BFU2015-68652-R","AGL2015-65684-C2-1-R"],"pubmed_authors":["Collado IG","Hanson JR","Hernandez-Galan R","Botubol-Ares JM"],"additional_accession":[]},"is_claimable":false,"name":"Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism.","description":"A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using <i>tert</i>-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed.","dates":{"release":"2017-01-01T00:00:00Z","publication":"2017 Jul","modification":"2024-10-18T04:13:52.753Z","creation":"2019-08-31T07:03:13Z"},"accession":"S-EPMC6641598","cross_references":{"pubmed":["31457640"],"doi":["10.1021/acsomega.7b00386"]}}