biostudies-literatureBotubol-Ares JMMinisterio de Econom?a y Competitividad3083-3090https://www.ebi.ac.uk/biostudies/studies/S-EPMC6641598biostudies-literatureUnknown2(7)A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using <i>tert</i>-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed.ACS omegaMild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism.PMC6641598BFU2015-68652-RAGL2015-65684-C2-1-RCollado IGHanson JRHernandez-Galan RBotubol-Ares JMfalseMild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism.A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using <i>tert</i>-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed.2017-01-01T00:00:00Z2017 Jul2024-10-18T04:13:52.753Z2019-08-31T07:03:13ZS-EPMC66415983145764010.1021/acsomega.7b00386