{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ayer SK"],"funding":["Duke University","National Institute of General Medical Sciences","NIGMS NIH HHS"],"pagination":["3508-3523"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6656367"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["84(6)"],"pubmed_abstract":["Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions."],"journal":["The Journal of organic chemistry"],"pubmed_title":["Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes."],"pmcid":["PMC6656367"],"funding_grant_id":["R35GM128741-01","R35 GM128741"],"pubmed_authors":["Ayer SK","Roizen JL"],"additional_accession":[]},"is_claimable":false,"name":"Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes.","description":"Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Mar","modification":"2024-11-20T23:54:48.264Z","creation":"2020-10-29T12:10:16Z"},"accession":"S-EPMC6656367","cross_references":{"pubmed":["30779561"],"doi":["10.1021/acs.joc.9b00105"]}}