{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Confer AM"],"funding":["Division of Chemistry","Johns Hopkins University","National Institute of General Medical Sciences","NIGMS NIH HHS"],"pagination":["9576-9580"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6715289"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["58(15)"],"pubmed_abstract":["The synthesis of a new nonheme iron NO binding complex, [Fe<sup>II</sup>(CH<sub>3</sub>CN)(N3Py<sup>2Ph</sup>SEtCN)](BF<sub>4</sub>)<sub>2</sub> (<b>1</b>), is reported. Complex <b>1</b>, which contains two sterically encumbering phenyl substituents, exhibits a high-spin (hs) Fe<sup>II</sup> (<i>S</i> = 2) ground state in contrast to the <i>S</i> = 0 ground state for unsubstituted [Fe<sup>II</sup>(CH<sub>3</sub>CN)(N3PySEtCN)(BF<sub>4</sub>)<sub>2</sub>. Reaction of <b>1</b> with NO<sub>(g)</sub> in CH<sub>3</sub>CN yields an {FeNO}<sup>7</sup> (<i>S</i> = <sup>3</sup>/<sub>2</sub>) complex <b>2</b>, which slowly decays at 25 °C with loss of NO<sup>•</sup> to regenerate <b>1</b>. One-electron reduction of <b>2</b> with Cr(C<sub>6</sub>H<sub>6</sub>)<sub>2</sub> at -40 °C yields the metasta"],"journal":["Inorganic chemistry"],"pubmed_title":["Mononuclear, Nonheme, High-Spin {FeNO}<sup>7/8</sup> Complexes Supported by a Sterically Encumbered N<sub>4</sub>S-Thioether Ligand."],"pmcid":["PMC6715289"],"funding_grant_id":["GM074785","1566007","R01 GM074785"],"pubmed_authors":["Confer AM","Moenne-Loccoz P","Sabuncu S","Siegler MA","Goldberg DP"],"additional_accession":[]},"is_claimable":false,"name":"Mononuclear, Nonheme, High-Spin {FeNO}<sup>7/8</sup> Complexes Supported by a Sterically Encumbered N<sub>4</sub>S-Thioether Ligand.","description":"The synthesis of a new nonheme iron NO binding complex, [Fe<sup>II</sup>(CH<sub>3</sub>CN)(N3Py<sup>2Ph</sup>SEtCN)](BF<sub>4</sub>)<sub>2</sub> (<b>1</b>), is reported. Complex <b>1</b>, which contains two sterically encumbering phenyl substituents, exhibits a high-spin (hs) Fe<sup>II</sup> (<i>S</i> = 2) ground state in contrast to the <i>S</i> = 0 ground state for unsubstituted [Fe<sup>II</sup>(CH<sub>3</sub>CN)(N3PySEtCN)(BF<sub>4</sub>)<sub>2</sub>. Reaction of <b>1</b> with NO<sub>(g)</sub> in CH<sub>3</sub>CN yields an {FeNO}<sup>7</sup> (<i>S</i> = <sup>3</sup>/<sub>2</sub>) complex <b>2</b>, which slowly decays at 25 °C with loss of NO<sup>•</sup> to regenerate <b>1</b>. One-electron reduction of <b>2</b> with Cr(C<sub>6</sub>H<sub>6</sub>)<sub>2</sub> at -40 °C yields the metasta","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Aug","modification":"2025-04-22T10:39:13.471Z","creation":"2020-10-29T17:07:43Z"},"accession":"S-EPMC6715289","cross_references":{"pubmed":["31328501"],"doi":["10.1021/acs.inorgchem.9b01475"]}}