{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Augustin AU"],"funding":["European Union (Horizon 2020)"],"pagination":["11620-11624"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6771889"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["25(50)"],"pubmed_abstract":["A 1,3-aminothiolation was realized by reacting 2-substituted cyclopropane 1,1-dicarboxylates with sulfonamides and N-(arylthio)succinimides. Under Sn(OTf)<sub>2</sub> catalysis the transformation proceeded smoothly to the corresponding ring-opened products bearing the sulfonamide in the 1-position next to the donor and the arylthio residue in the 3-position next to the acceptor. The procedure was extended to the corresponding selenium analogues by employing N-(phenylseleno)succinimides as an electrophilic selenium source."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["Ring-Opening 1,3-Aminochalcogenation of Donor-Acceptor Cyclopropanes: A Three-Component Approach."],"pmcid":["PMC6771889"],"funding_grant_id":["GAINBYSTRAIN"],"pubmed_authors":["Augustin AU","Jones PG","Werz DB"],"additional_accession":[]},"is_claimable":false,"name":"Ring-Opening 1,3-Aminochalcogenation of Donor-Acceptor Cyclopropanes: A Three-Component Approach.","description":"A 1,3-aminothiolation was realized by reacting 2-substituted cyclopropane 1,1-dicarboxylates with sulfonamides and N-(arylthio)succinimides. Under Sn(OTf)<sub>2</sub> catalysis the transformation proceeded smoothly to the corresponding ring-opened products bearing the sulfonamide in the 1-position next to the donor and the arylthio residue in the 3-position next to the acceptor. The procedure was extended to the corresponding selenium analogues by employing N-(phenylseleno)succinimides as an electrophilic selenium source.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Sep","modification":"2025-04-04T08:26:30.275Z","creation":"2019-10-16T07:05:46Z"},"accession":"S-EPMC6771889","cross_references":{"pubmed":["31282001"],"doi":["10.1002/chem.201902160"]}}