{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Vanni M"],"funding":["Ministero dell?Istruzione, dell?Universit? e della Ricerca","European Research Council"],"pagination":["5075-5080"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6804426"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["31(14)"],"pubmed_abstract":["The burgeoning interest in two-dimensional (2D) black phosphorus (bP) contributes to the expansion of its applications in numerous fields. In the present study, 2D bP is used as a support for homogeneously dispersed palladium nanoparticles directly grown on it by a wet chemical process. Electron energy loss spectroscopy-scanning transmission electron microscopy analysis evidences a strong interaction between palladium and P atoms of the bP nanosheets. A quantitative evaluation of this interaction comes from the X-ray absorption spectroscopy measurements that show a very short Pd-P distance of 2.26 Å, proving for the first time the existence of an unprecedented Pd-P coordination bond of a covalent nature. Additionally, the average Pd-P coordination number of about 1.7 reveals that bP acts a"],"journal":["Chemistry of materials : a publication of the American Chemical Society"],"pubmed_title":["Black Phosphorus/Palladium Nanohybrid: Unraveling the Nature of P-Pd Interaction and Application in Selective Hydrogenation."],"pmcid":["PMC6804426"],"funding_grant_id":["PRIN 2015 20154X9ATP","670173"],"pubmed_authors":["Giaccherini A","Mio AM","Spinella C","Caporali M","Banchelli M","Heun S","D'Acapito F","Caporali S","Serrano-Ruiz M","Peruzzini M","Vanni M","Matteini P","Nicotra G","Telesio F"],"additional_accession":[]},"is_claimable":false,"name":"Black Phosphorus/Palladium Nanohybrid: Unraveling the Nature of P-Pd Interaction and Application in Selective Hydrogenation.","description":"The burgeoning interest in two-dimensional (2D) black phosphorus (bP) contributes to the expansion of its applications in numerous fields. In the present study, 2D bP is used as a support for homogeneously dispersed palladium nanoparticles directly grown on it by a wet chemical process. Electron energy loss spectroscopy-scanning transmission electron microscopy analysis evidences a strong interaction between palladium and P atoms of the bP nanosheets. A quantitative evaluation of this interaction comes from the X-ray absorption spectroscopy measurements that show a very short Pd-P distance of 2.26 Å, proving for the first time the existence of an unprecedented Pd-P coordination bond of a covalent nature. Additionally, the average Pd-P coordination number of about 1.7 reveals that bP acts a","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Jul","modification":"2025-04-22T10:06:42.305Z","creation":"2019-11-05T08:09:20Z"},"accession":"S-EPMC6804426","cross_references":{"pubmed":["31656368"],"doi":["10.1021/acs.chemmater.9b00851"]}}