{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Empel C"],"funding":["European Research Council"],"pagination":["11316-11322"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6900254"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["84(17)"],"pubmed_abstract":["Metal-free N-H functionalization reactions represent an important strategy for sustainable C-N coupling reactions. In this report, we describe the visible light photolysis of aryl diazoacetates in the presence of some <i>N-</i>heterocycles that enables mild, metal-free N-H functionalization reactions of carbazole and azepine heterocycles (15 examples, up to 83% yield)."],"journal":["The Journal of organic chemistry"],"pubmed_title":["Visible Light Induced Metal-Free Carbene <i>N</i>-Carbazolation."],"pmcid":["PMC6900254"],"funding_grant_id":["716136"],"pubmed_authors":["Koenigs RM","Empel C","Patureau FW"],"additional_accession":[]},"is_claimable":false,"name":"Visible Light Induced Metal-Free Carbene <i>N</i>-Carbazolation.","description":"Metal-free N-H functionalization reactions represent an important strategy for sustainable C-N coupling reactions. In this report, we describe the visible light photolysis of aryl diazoacetates in the presence of some <i>N-</i>heterocycles that enables mild, metal-free N-H functionalization reactions of carbazole and azepine heterocycles (15 examples, up to 83% yield).","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Sep","modification":"2021-02-20T21:46:13Z","creation":"2020-05-21T21:24:46Z"},"accession":"S-EPMC6900254","cross_references":{"pubmed":["31373201"],"doi":["10.1021/acs.joc.9b01753"]}}