{"database":"biostudies-literature","file_versions":[],"scores":{"citationCount":0,"reanalysisCount":0,"viewCount":41,"searchCount":0},"additional":{"submitter":["Vogt CG"],"funding":["Bundesministerium für Bildung und Forschung"],"pagination":["18942-18947"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC6972522"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["58(52)"],"pubmed_abstract":["The milling ball is the catalyst. We introduce a palladium-catalyzed reaction inside a ball mill, which makes catalyst powders, ligands, and solvents obsolete. We present a facile and highly sustainable synthesis concept for palladium-catalyzed C-C coupling reactions, exemplarily showcased for the Suzuki polymerization of 4-bromo or 4-iodophenylboronic acid giving poly(para-phenylene). Surprisingly, we observe one of the highest degrees of polymerization (199) reported so far."],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization."],"pmcid":["PMC6972522"],"funding_grant_id":["03SF0498"],"pubmed_authors":["Halasz I","Borchardt L","Vogt CG","Evans JD","Etter M","Gratz S","Lukin S"],"view_count":["41"],"additional_accession":[]},"is_claimable":false,"name":"Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization.","description":"The milling ball is the catalyst. We introduce a palladium-catalyzed reaction inside a ball mill, which makes catalyst powders, ligands, and solvents obsolete. We present a facile and highly sustainable synthesis concept for palladium-catalyzed C-C coupling reactions, exemplarily showcased for the Suzuki polymerization of 4-bromo or 4-iodophenylboronic acid giving poly(para-phenylene). Surprisingly, we observe one of the highest degrees of polymerization (199) reported so far.","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Dec","modification":"2021-02-21T09:38:14Z","creation":"2020-05-22T08:54:22Z"},"accession":"S-EPMC6972522","cross_references":{"pubmed":["31593331"],"doi":["10.1002/anie.201911356"]}}